STRUCTURAL PROPERTIES OF MXENE AND NANOCELLULOSE AND THEIR APPLICATION POTENTIAL
https://doi.org/10.53360/2788-7995-2025-3(19)-68
Abstract
In the modern era of rapid scientific and technological advancement, the preservation of the environment and natural resources has become increasingly important. In this context, there is growing interest in environmentally friendly, renewable, and highly efficient materials. MXene and nanocellulose are two promising nanomaterials that have attracted considerable scientific attention over the past decade. Their unique structural, chemical, and physical properties, as well as their multifunctionality, make them applicable across a wide range of fields.
MXene is a two-dimensional material derived from the selective etching of MAX phases. Due to its high conductivity, hydrophilicity, thermal and chemical stability, and tunability, it is widely studied in water purification, energy storage, electronics, sensors, and biomedical applications. Nanocellulose, a bio-based, biodegradable material obtained from plant cellulose, offers high mechanical strength, a large surface area, and chemical stability, making it a valuable material in medicine, food packaging, and nanocomposites.
This article provides a detailed review of synthesis methods for these materials (e.g., HF or LiF/HCl etching for MXene, and acid hydrolysis, mechanical, and enzymatic treatment for nanocellulose), along with their morphological and structural characteristics. It also explores their individual and combined application potentials, particularly in nanocomposites and membrane systems. The analysis shows that due to their compatibility and high functionality, these materials may serve as essential components in future green technologies aimed at solving ecological and technogenic challenges.
About the Authors
A. T. TabynbayevaKazakhstan
Aidana Tabynbayeva – Master’s student, Department of Chemical Physics and Materials Science
050038, Rеpublic of Kazakhstan, Almaty, Al-Farabi av,71
M. E. Suleimenova
Kazakhstan
Madina Suleimenova – Master of Chemical Technology, Researcher at the Department of Chemical Physics and Materials Science
050038, Rеpublic of Kazakhstan, Almaty, Al-Farabi av,71
K. T. Tastambek
Kazakhstan
Kuanysh Tastambek – PhD, director, SRI Sustainability of ecology and bioresources
050038, Rеpublic of Kazakhstan, Almaty, Al-Farabi av,71
161200, Rеpublic of Kazakhstan, Turkestan, B.Sattarkhanov Ave., 29
N. S. Akimbekov
Kazakhstan
Nuraly Akimbekov – PhD, professor of the research institute
«Ecology and sustainability of Bioresources»
050038, Rеpublic of Kazakhstan, Almaty, Al-Farabi av,71
161200, Rеpublic of Kazakhstan, Turkestan, B.Sattarkhanov Ave., 29
Z. T. Tauanov
Kazakhstan
Zhandos Tauanov – PhD, associate professor-researcher
050038, Rеpublic of Kazakhstan, Almaty, Al-Farabi av,71
161200, Rеpublic of Kazakhstan, Turkestan, B.Sattarkhanov Ave., 29
References
1. Akhter R. MXenes: A comprehensive review of synthesis, properties, and progress in supercapacitor applications / R. Akhter, S.S. Maktedar // Journal of Materiomics. – 2023. – vol. 9, № 6. – Р. 1196-1241. https://doi.org/10.1016/J.JMAT.2023.08.011.
2. Facile Fabrication of Densely Packed Ti3C2MXene/Nanocellulose Composite Films for Enhancing Electromagnetic Interference Shielding and Electro-/Photothermal Performance / Z. Zhou et al // ACS Nano. – 2021. – vol. 15, № 7. – Р. 12405-12417. https://doi.org/10.1021/acsnano.1c04526.
3. Gogotsi Y. MXenes: Two-Dimensional Building Blocks for Future Materials and Devices / Y. Gogotsi, Q. Huang // ACS Nano. – 2021. – vol. 15, № 4. – Р. 5775-5780. https://doi.org/10.1021/acsnano.1c03161.
4. Elastic properties and tensile strength of 2D Ti3C2Tx MXene monolayers / C. Rong et al. // Nat Commun. – 2024. – vol. 15, № 1. – Р. 1566. https://doi.org/10.1038/s41467-024-45657-6.
5. High electrical conductivity and breakdown current density of individual monolayer Ti3C2T MXene flakes / A. Lipatov et al. // Matter. – 2021. – vol. 4, № 4. – Р. 1413-1427. https://doi.org/10.1016/j.matt.2021.01.021.
6. Transforming Ti3C2Tx MXene’s intrinsic hydrophilicity into superhydrophobicity for efficient photothermal membrane desalination / B. Zhang et al. // Nat Commun. – 2022. – vol. 13, № 1. – Р. 3315. https://doi.org/10.1038/s41467-022-31028-6.
7. Role of Surface Terminations for Charge Storage of Ti 3 C 2 T x MXene Electrodes in Aqueous Acidic Electrolyte / L. Liu et al // Angewandte Chemie International Edition. – 2024. – vol. 63, № 14. https://doi.org/10.1002/anie.202319238.
8. Understanding the Chemical Degradation of Ti 3 C 2 T x MXene Dispersions: A Chronological Analysis / K.P. Marquez et al. // Small Science. – 2024. https://doi.org/10.1002/smsc.202400150.
9. Harja M. Recent advances in removal of Congo Red dye by adsorption using an industrial waste / M. Harja, G. Buema, D. Bucur // Sci Rep. – vol. 12, № 1. – Р. 1-18. https://doi.org/ 10.1038/s41598-022- 10093-3.
10. In Situ Synthesis of MXene with Tunable Morphology by Electrochemical Etching of MAX Phase Prepared in Molten Salt / L. Liu et al // Adv Energy Mater. – 2023. – vol. 13, № 7. https://doi.org/10.1002/aenm.202203805.
11. Advancements in MXenes and mechanochemistry: exploring new horizons and future applications / S. Iravani et al // Mater Adv. – 2024. – vol. 5, № 21. – Р. 8404-8418. https://doi.org/10.1039/D4MA00775A.
12. Direct synthesis and chemical vapor deposition of 2D carbide and nitride Mxenes / D. Wang et al. // Science. – 2023. – vol. 379, № 6638. – Р. 1242-1247. https://doi.org/ 10.1126/science.add9204.
13. Huang L. MXene‐Based Membranes for Separation Applications / L. Huang, L. Ding, H. Wang // Small Science. – 2021. – vol. 1, № 7. https://doi.org/10.1002/smsc.202100013.
14. Cellulose nanofibrils manufactured by various methods with application as paper strength additives / J. Zeng et al // Sci Rep. – 2021. – vol. 11, № 1. – Р. 1-16. https://doi.org/10.1038/s41598-021-91420-y.
15. A review of nanocellulose as a new material towards environmental sustainability / K. Dhali et al // Science of The Total Environment. – 2021. – vol. 775. – Р. 145871. https://doi.org/10.1016/J.SCITOTENV.2021.145871.
16. Emerging developments regarding nanocellulose-based membrane filtration material against microbes / M.N.F. Norrrahim et al // Polymers (Basel). – 2021. – vol. 13, № 19. https://doi.org/10.3390/polym13193249.
17. Barja F. Bacterial nanocellulose production and biomedical applications / F. Barja // J Biomed Res. – 2021. – vol. 35, № 4. – Р. 310-317. https://doi.org/10.7555/JBR.35.20210036.
18. Production of nanocellulose from lignocellulosic biomass and its potential applications: A review / M. N. Khan et al // Global Nest Journal. – 2024. – vol. 26, № 4. https://doi.org/10.30955/gnj.005604.
19. Production of nanocellulose from lignocellulosic biomass and its potential applications: A review / M.N. Khan et al // Global Nest Journal. – 2024. – vol. 26, № 4. https://doi.org/10.30955/gnj.005604.
20. A comprehensive review of cellulose nanomaterials for adsorption of wastewater pollutants: focus on dye and heavy metal Cr adsorption and oil/water separation / Y. Yang et al // Collagen and Leather. – 2024. – vol. 6, № 1. – Р. 1-25. https://doi.org/10.1186/s42825-024-00179-1.
21. Recycling of TEMPO-mediated oxidation medium and its effect on nanocellulose properties / H. Xu et al // Carbohydr Polym. – 2023. – vol. 319. – Р. 121168. https://doi.org/10.1016/J.CARBPOL.2023.121168.
22. Preparation and characterization of nanocellulose obtained by TEMPO-mediated oxidation of organosolv pulp from reed stalks / V.A. Barbash et al // Appl Nanosci. – 2022. – vol. 12, № 4. – Р. 835-848. https://doi.org/10.1007/s13204-021- 01749-z.
23. Nanocrystalline cellulose isolation via acid hydrolysis from non-woody biomass: Importance of hydrolysis parameters / A.Q. Almashhadani et al // Carbohydr Polym. – 2022. – vol. 286. – Р. 119285. https://doi.org/10.1016/J.CARBPOL.2022.119285.
24. Entangled cellulose nanofibers produced from sugarcane bagasse via alkaline treatment, mild acid hydrolysis assisted with ultrasonication / M. Asem et al // Journal of King Saud University – Engineering Sciences. – 2023. – vol. 35, № 1. – Р. 24-31. https://doi.org/10.1016/j.jksues.2021.03.003.
25. Cellulose nanofibrils (CNFs) produced by different mechanical methods to improve mechanical properties of recycled paper / F. Hu et al // Carbohydr Polym. – 2021. – vol. 254. – Р. 117474. https://doi.org/10.1016/J.CARBPOL.2020.117474.
26. Preparation of cellulose nanofibers from potato residues by ultrasonication combined with highpressure homogenization / X. Liu et al // Food Chem. – 2023. – vol. 413. – Р. 135675. https://doi.org/10.1016/J.FOODCHEM.2023.135675.
27. Samsalee N. Rice husk nanocellulose: Extraction by high-pressure homogenization, chemical treatments and characterization / N. Samsalee, J. Meerasri, R. Sothornvit // Carbohydrate Polymer Technologies and Applications. – 2023. – vol. 6. – Р. 100353. https://doi.org/10.1016/J.CARPTA.2023.100353.
28. Ultrasonic cavitation: An effective cleaner and greener intensification technology in the extraction and surface modification of nanocellulose / D.Y. Hoo et al // Ultrason Sonochem. – 2022. – vol. 90. – Р. 106176. https://doi.org/10.1016/J.ULTSONCH.2022.106176.
29. Preparation and characterization of nanocellulose fiber (CNF) by biological enzymatic method,” / J. Wang et al // Journal of Thermoplastic Composite Materials. – 2024. – vol. 37, № 3. – Р. 1223-1241. https://doi.org/10.1177/08927057231180479.
30. Pradhan D. Emerging technologies for the production of nanocellulose from lignocellulosic biomass / D. Pradhan, A.K. Jaiswal, S. Jaiswal // Carbohydr Polym. – 2022. – vol. 285. – Р. 119258. https://doi.org/10.1016/J.CARBPOL.2022.119258.
31. Cellulose nanostructures obtained using enzymatic cocktails with different compositions / T.J. Bondancia et al // Int J Biol Macromol. – 2022. – vol. 207. – Р. 299-307. https://doi.org/10.1016/J.IJBIOMAC.2022.03.007.
32. Exploration of a novel and efficient source for production of bacterial nanocellulose, bioprocess optimization and characterization / N.E.-A. El-Naggar et al // Sci Rep. – 2022. – vol. 12, № 1. – Р. 18533. https://doi.org/10.1038/s41598-022-22240-x.
33. Bacterial nanocellulose: Optimized synthesis and biomedical applications / Y. Zhou et al // Ind Crops Prod. – vol. 205. – Р. 117589. https://doi.org/10.1016/J.INDCROP.2023.117589.
34. Synthesis of Nanocellulose as a Sustainable Construction Material from Waste Paper Using the Alkaline Method at Low Temperature / P. Suanto et al // Civil Engineering and Architecture. – 2025. – vol. 13, № 1. – Р. 175-192. https://doi.org/10.13189/cea.2025.130110.
35. Bacha E.G. Extraction and Characterization of Nanocellulose from Eragrostis Teff Straw / E.G. Bacha, H.D. Demsash // Journal of cellulose. – 2021.
36. Nanocellulose from oil palm biomass to enhance microbial fermentation of butanol for bioenergy applications / N. Hastuti et al // Bioresources. – 2019. – vol. 14, № 3. – Р. 6936-6957. https://doi.org/10.15376/biores.14.3.6936-6957.
37. S. Głowniak and B. Szcz Recent Developments in Sonochemical Synthesis of Nanoporous Materials. – 2023.
38. Cellulose nanofibrils (CNFs) produced by different mechanical methods to improve mechanical properties of recycled paper / F. Hu et al // Carbohydr Polym. – 2021. – vol. 254. – Р. 117474. https://doi.org/10.1016/J.CARBPOL.2020.117474.
39. A comprehensive review of cellulose nanomaterials for adsorption of wastewater pollutants: focus on dye and heavy metal Cr adsorption and oil/water separation / Y. Yang et al // Collagen and Leather. – 2024. – vol. 6, № 1. – Р. 1-25. https://doi.org/10.1186/s42825-024-00179-1.
Review
For citations:
Tabynbayeva A.T., Suleimenova M.E., Tastambek K.T., Akimbekov N.S., Tauanov Z.T. STRUCTURAL PROPERTIES OF MXENE AND NANOCELLULOSE AND THEIR APPLICATION POTENTIAL. Bulletin of Shakarim University. Technical Sciences. 2025;(3(19)):612-623. (In Kazakh) https://doi.org/10.53360/2788-7995-2025-3(19)-68
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