RESEARCH OF THE PHYSICAL PROPERTIES OF MULTI-COMPONENT, MULTILAYER, SOLID NANOCOMPOSITE COATINGS
https://doi.org/10.53360/2788-7995-2024-1(13)-38
Abstract
The results of studies of the physical and mechanical properties of nitride and carbide multilayer systems based on ((TiZrNbTa)N, depending on the methods of deposition and heat treatment are analyzed and summarized. The coatings were deposited by magnetron sputtering. Studies of the original and processed alloy samples were carried out in a regional engineering laboratory. When extremely high doses of N+ ions (1018 cm-2) are introduced into nanostructured coatings (TiZrNbTa)N, a multilayer structure is formed, consisting of amorphous, nanocrystalline (dispersed) and nanostructured layers.The hardness of the coatings decreases to 12 GPa in the near-surface region, and then increases with depth, reaching a maximum of 23 GPa at great depths ≥ 200 nm.
Sputtering a small layer of the coating surface, leading to the elimination of the droplet fraction formed during cathode erosion during vacuum-arc sputtering, is the reason for the decrease in the microhardness of the implanted samples.
About the Authors
A. KasymbaevKazakhstan
Alexey Kasymbaev – student at VKTU in the direction of «Technical Physics»
070004, Republic of Kazakhstan, Ust-Kamenogorsk, Protozanova 69 st. 2
S. V. Plotnikov
Sergey Viktorovich Plotnikov – Doctor of Physical and Mathematical Sciences
070004, Republic of Kazakhstan, Ust-Kamenogorsk, Protozanova 69 st. 2
A. Turlybekuly
Kazakhstan
Amanzhol Turlybekuly – Senior Researcher, Ph.D
010000, Republic of Kazakhstan, 56, Sauran 5g, Astana
A. Pogrebnyak
Ukraine
Alexander Dmitrievich Pogrebnyak – Doctor of Physical and Mathematical Sciences, Head of the Department of Nanoelectronics and Surface Modification
40007, Ukraine, Sumy, 2 Rimsky-Korsakov st.
References
1. Peculiarities of Structure State and Mechanical Characteristics in ion-Plasma Condensates of Quasibinary System Borides W2B5-TiB2 / O.V. Sobol, O.N. Grigorjev, Yu.A. Kunitsky et al // Science of Sintering. – 2006. – V. 38. – P. 63-72. (In English).
2. Sobol O.V. Kontsentratsionno-strukturnoe uporyadochenie v nano-kristallicheskikh ionnoplazmennykh kondensatakh (W,Ti)C tverdogo rastvora / O.V. Sobol' // FIP. – 2007. – T. 5, № 1. – S. 69 -74. (In Russian).
3. Sobol O.V. Protsess nanostrukturnogo uporyadocheniya v kondensatakh sistemy W-Ti-B / O.V. Sobol' // FTT. – 2007. – T. 49, Vyp. 6. – S. 1104-1110. (In Russian).
4. Sobol O.V. Study of concentration and structural ordering in nanocrystal-line ion-plasma condensates of (W, Ti)C solid solution / O.V. Sobol // Functional Materials. – 2007. – Vol.14, № 3. – P. 392-397. (In Russian).
5. Sobol O.V. Osobennosti fazovogo sostava, struktury, napryazhennogo sostoyaniya i mekhanicheskikh kharakteristik kondensatov boridnoi sistemy W-Ti-B, poluchennykh triodnym raspyleniem / O.V. Sobol', S.N. Dub, O.N. Grigor'ev i dr.// Sverkhtverdye materialy. – 2005. – № 5. – S. 38-47. (In Russian).
6. Haines J. Synthesis and design of superhard materials / J. Haines, J.M. Leger, G. Bocquillon // Annu. Rev. Mater. Res. – 2001. – V. 31. – P. 1-23. (In English).
7. Mayrhofer P.H. Ab iuito calculated binodal and spinodal of cubic Ti1-xAlxN / P.H. Mayrhofer, D. Music, J.M. Schneider // Appl. Phys. Letter. – 2006. – V.88. – P. 071922. (In English).
8. Zhang R.F. Veprek S. Metastable phases and spinodal decomposition in Ti1-xAlxN system studied by ab initio and thermodynamic modeling, a comparison with the TiN–Si3N4 system / R.F. Zhang, S. Veprek // Mater. Sci. Eng., A. – 2007. – V.448. – P.111-119. (In English).
9. Microstructure, physical and chemical properties of nanostructured (Ti-Hf-Zr-V-Nb)N coatings under different deposition conditions / A.D. Pogrebnjak, I.V. Yakushchenko, A.A. Bagdasaryan et al // Mater. Chem. Phys. 2014. – Vol. 147, № 3. – P. 1079-1091. (In English).
10. 10 Sobol O.V. Influence of Ion Implantation on the Structural and Stressed State and Mechanical Properties of Nitrides of High-entropy (TiZrAlYNb)N and (TiZrHfVNbTa)N Alloys / O.V. Sobol, I.V. Yakushchenko // J. Nano- Electron. Phys. – 2015. – Vol.7, № 3. – P. 03044-1 - 03044-6. (In English).
11. 11 Pogrebnjak A.D. The structure and properties of high-entropy alloys and nitride coatings based on them / A.D. Pogrebnjak, A.A. Bagdasaryan, I.V. Yakushchenko, V.M. Beresnev // Rus. Chem. Rev. – 2014. – Vol.83, № 11. – P. 1027-1061. (In English).
Review
For citations:
Kasymbaev A., Plotnikov S.V., Turlybekuly A., Pogrebnyak A. RESEARCH OF THE PHYSICAL PROPERTIES OF MULTI-COMPONENT, MULTILAYER, SOLID NANOCOMPOSITE COATINGS. Bulletin of Shakarim University. Technical Sciences. 2024;(1(13)):312-319. (In Russ.) https://doi.org/10.53360/2788-7995-2024-1(13)-38