DEVELOPMENT OF A METHOD FOR PURIFICATION AND UTILIZATION OF USED MOTOR OILS USING BENTONITE SORBENTS
https://doi.org/10.53360/2788-7995-2026-2(22)-73
Abstract
The study examines modern approaches to oil regeneration, including physical, chemical, and sorption methods, and substantiates the choice of adsorption purification as an environmentally safe and technologically simple alternative. An effective method for the purification and utilization of used motor oils using natural and modified bentonite sorbents has been developed. The research objects included used KIXX 10W-40 motor oil, P1T1A and «13 Horizon» bentonites, as well as their modified forms obtained through acid and peroxide activation methods. Experimental studies were carried out using a vacuum oil purification unit and sorption filtration techniques. The purification efficiency was evaluated using FTIR spectroscopy, thermogravimetric analysis (TGA), and ICP-MS methods. The results demonstrated a significant reduction in water content, oxidation products, sulfur-containing compounds, and metal impurities. The highest efficiency was achieved with modified P1T1A bentonite, ensuring maximum contaminant removal. It was established that modification increases specific surface area and sorption capacity, enhancing adsorption processes. The proposed method is simple, cost-effective, scalable, and does not generate secondary toxic waste, making it suitable for industrial application while reducing environmental impact.
About the Authors
A. N. SabitovaKazakhstan
Аlfira Nurzhanovna Sabitova – PhD, associate professor, Head of the Department Chemistry and Ecology,
071412, Semey, Glinki street, 20
Zh. Sh. Sharipkhan
Kazakhstan
Zhanna Sharipkhankyzy Sharipkhan – PhD -student, Department Chemistry and Ecology,
071412, Semey, Glinki street, 20
B. B. Bayakhmetova
Kazakhstan
Bulbul Bayakmetkyzy Bayakhmetova – Cand. Chem.Sci., associate, Department Chemistry and Ecology,
071412, Semey, Glinki street, 20
A. K. Kabylkakov
Kazakhstan
Amirzhan Kuanyshuly Kabylkakov – stundent, Department Chemistry and Ecology,
071412, Semey, Glinki street, 20
N. N. Nurgaliyev
Kazakhstan
Nurzhаn Nurlybеkuly Nurgаliyеv – PhD, associate professor-researcher, Dеpаrtmеnt of Chеmistry аnd Ecology,
071412, Semey, Glinki street, 20
References
1. Association “Resource.” 2023. REO: Only 25% of 2 million tons of used lubricating oils are collected for recycling in Russia. https://reo.ru
2. Vazquez-Duhalt, R. 1989. Environmental impact of used motor oil. Science of the Total Environment, 79(1), 1-23.
3. GlobeCore. (n.d.). Regeneration of used oil: reality and perspectives. Retrieved from https://globecore.com/publications/regeneration-used-oil/
4. Sazzad, M. R. I., Rahman, M. R., Hassan, T., Al Rifat, A., Al Mamun, A., Adib, A. R., Meraz, R. M., & Ahmed, M. 2024. Advancing sustainable lubricating oil management: Re-refining techniques, market insights, innovative enhancements, and conversion to fuel. Heliyon, 10(20), e39248.
5. European Commission. 2023. Technical report: Waste oils management in the EU (COM(2023) 670 final). https://eur-lex.europa.eu/legal-content/EN/TXT/?uri=CELEX:52023DC0670
6. Rajaković-Ognjanović, V., Aleksić, G., & Rajaković, Lj. 2008. Governing factors for motor oil removal from water with different sorption materials. Journal of Hazardous Materials, 154(1-3), 558-563.
7. Ewis, D., Mahmud, N., Benamor, A., Ba-Abbad, M. M., Nasser, M., & El-Naas, M. 2022. Enhanced removal of diesel oil using new magnetic bentonite-based adsorbents combined with different carbon sources. Water, Air, & Soil Pollution, 233, Article 195.
8. Teneqja, V., & Drushku, S. 2015. Activation of Kosovo bentonite with sulphuric acid for recycling of used motor oils. Journal of International Environmental Application & Science, 10(4), 408-413.
9. Durrani, H. A. 2014. Chemistry and recycling technology of used motor oil. International Journal of Engineering Sciences & Research Technology, 3(3), 1216-1220.
10. Cheon, Y., Kim, S., & Jeong, H. Y. 2025. Effects of thermal treatment on bentonite stability and europium(III) leachability. Journal of Analytical Science and Technology, 16(1), 6.
11. Ghoubali, N. E., Maaroufi, A., Hamidi, A. E., et al. 2025. Unlocking the energy potential of Moroccan bentonite clay: structural, optical, and thermal insights for advanced applications. Discover Applied Sciences, 7, 887.
12. Hebbar, R. S., Isloor, A. M., Prabhu, B., & Ismail, A. F. 2018. Removal of metal ions and humic acids through polyetherimide membrane with grafted bentonite clay. Scientific Reports, 8(1), 4939.
13. Cheon, Y., Kim, S., & Jeong, H. Y. 2025. Effects of thermal treatment on bentonite stability and europium(III) leachability. Journal of Analytical Science and Technology, 16(1), 6.
14. Hebbar, R. S., Isloor, A. M., Prabhu, B., & Ismail, A. F. 2018. Removal of metal ions and humic acids through polyetherimide membrane with grafted bentonite clay. Scientific Reports, 8(1), 4939.
15. Yang, X., Li, Y., Gan, M., et al. 2025. Adsorption and desorption effect of modified bentonite on soil heavy metal Pb/Cd and the feasibility assessment of reducing the ecotoxicity. Environmental Sciences Europe, 37(1), 105.
16. Hebbar, R. S., Isloor, A. M., Prabhu, B., & Ismail, A. F. 2018. Removal of metal ions and humic acids through polyetherimide membrane with grafted bentonite clay. Scientific Reports, 8(1), 4939.
17. Aguilar, J., Almeida-Naranjo, C., Aldás, M. B., & Guerrero, V. H. 2020. Acid activation of bentonite clay for recycled automotive oil purification. E3S Web of Conferences, 191, 03002.
18. Singh, H., Gupta, R., & Singh, A. 2022. Regeneration of used lubricating oil by novel clay-based adsorbents: A comparative FTIR study. Journal of Environmental Chemical Engineering, 10(1), 106987.
19. Wolak, A., Krasodomski, W., & Zając, G. 2020. FTIR analysis and monitoring of used synthetic oils operated under similar driving conditions. Friction, 8, 995-1006.
20. Onukwuli, O. D., & Emembolu, L. N. 2017. Metal ions adsorption from used lubricating oil using modified clays. Chemical Engineering Communications, 204(9), 1063-1073.
21. Oliveira, A. A., da Silva, M. L., & Dos Santos, W. T. P. 2021. Adsorption of metals and organics from spent oils using peroxide-activated bentonites. Environmental Technology, 42(1), 82-92.
22. Sharma, B. K., & Rashid, M. 2016. Used lubricating oil regeneration using advanced clay treatment. Journal of Environmental Management, 181, 806-813.
Review
For citations:
Sabitova A.N., Sharipkhan Zh.Sh., Bayakhmetova B.B., Kabylkakov A.K., Nurgaliyev N.N. DEVELOPMENT OF A METHOD FOR PURIFICATION AND UTILIZATION OF USED MOTOR OILS USING BENTONITE SORBENTS. Bulletin of Shakarim University. Technical Sciences. 2026;(2(22)):715-725. (In Russ.) https://doi.org/10.53360/2788-7995-2026-2(22)-73
JATS XML















