MODERN APPROACHES TO THE USE OF MODIFIERS IN WATER-ACRYLIC FILM-FORMING SYSTEMS
https://doi.org/10.53360/2788-7995-2026-1(21)-70
Abstract
Acrylic water-dispersion coatings occupy a significant place in the market due to their environmental friendliness, technological flexibility and versatility of application. However, in order to ensure stable performance characteristics such as adhesion, strength, elasticity and resistance to external influences, targeted modification of formulation compositions is necessary. The use of modifiers makes it possible to adapt the properties of compositions to the specific conditions of application and operation, as well as to ensure highquality paintwork. This article provides an overview of existing approaches to the use of modifiers in wateracrylic film-forming compositions and their effect on the properties of finished coatings. The purpose of the article is to systematize data on the use of modifying additives in acrylic aqueous dispersions, analyze their functional purpose, and evaluate the impact on the technological and operational characteristics of coatings. Conclusion. The review identifies current trends in the development and application of modifiers in acrylic water-dispersion systems, emphasizing the need for further research to optimize formulations, improve component compatibility, and develop new highly effective additives.
About the Authors
D. Yu. OstrovnayaKazakhstan
Darya Yurievna Ostrovnaya – doctoral student
150000, Petropavlovsk, Pushkin street, 86
A. N. Dyuryagina
Kazakhstan
Antonina Nikolayevna Dyuryagina – Candidate of chemical sciences, Professor
150000, Petropavlovsk, Pushkin street, 86
Yu. S. Byzova
Kazakhstan
Yuliya Sergeevna Byzova – PhD
150000, Petropavlovsk, Pushkin street, 86
References
1. Weiss K.D. Paint and coatings: A mature industry in transition / K.D. Weiss //Progress in Polymer Science. – 1997. – № 22. – Р. 203-245. https://doi.org/10.1016/S0079-6700(96)00019-1.
2. Emulsifiers with high chemical resistance: a key to high performance waterborne coatings / V. Duecoffre et al // Progress in Organic Coatings. – 1998. – № 34. – Р. 200-205. https://doi.org/10.1016/S0300-9440(98)00015-4.
3. Wegmann A. Chemical resistance of waterborne epoxy/amine coatings / A. Wegmann // Progress in Organic Coatings. – 1997. – № 32. – Р. 231-239. https://doi.org/10.1016/S0300-9440(97)00011-1.
4. Volatile Chemical Products Emerging as Largest Petrochemical Source of Urban Organic Emissions / B.C. McDonald еt al // Science. – 2018. – № 359. – Р. 760-764. https://doi.org/10.1126/science.aaq0524.
5. Update on Volatile Organic Compound (VOC) Source Profiles and Ozone Formation Potential in Synthetic Resins Industry in China / Y. Ma et al // Environmental Pollution. – 2021. – № 291. – 118253. https://doi.org/10.1016/j.envpol.2021.118253.
6. Mukhamedgaliev B.A. Tekhnologiya sinteza polimernykh modifikatorov dlya lakokrasochnykh materialov / B.A. Mukhamedgaliev // Khimicheskaya promyshlennost’. – 2005. – № 3. – Р. 41-43.
7. A multi–functional coating based on acrylic copolymer modified with PDMS through copolymerization / J. Sha et al // Progress in Organic Coatings. – 2021. – № 156. – 106254. https://doi.org/10.1016/j.porgcoat.2021.106254.
8. Advances in Waterborne Acrylic Resins: Synthesis Principle, Modification Strategies, and Their Applications / C. Jiao et al // ACS Omega. – 2021. – № 6. – Р. 2443-2449. https://doi.org/10.1021/acsomega.0c05277.
9. Recent Advances in Combining Waterborne Acrylic Dispersions with Biopolymers / J. SoleraSendra et al // Polymers. – 2025. – № 17. – Р. 1027. https://doi.org/10.3390/polym17081027.
10. Winnik M.A. Film Formation from Latex / M.A. Winnik // Advances in Colloid and Interface Science. – 1997. https://doi.org/10.1016/S0001-8686(96)00307-5.
11. Zarras P. Handbook of Waterborne Coatings / P. Zarras, M.D. Soucek, A. Tiwari // Elsevier Science. – 2020. – 356 p.
12. Tracton A.A. Coatings Technology Handbook / A.A. Tracton // CRC Press. – 2006, 936 p.
13. Minimum Film Formation Temperature: Measurement and Significance / B. Meurer et al // Progress in Organic Coatings, 2001. https://doi.org/10.1016/S0300-9440(00)00139-7.
14. Routh A.F. Drying of thin colloidal films / A.F. Routh // Reports on Progress in Physics. – 2013. – № 76. – Р. 046603. https://doi.org/10.1088/0034-4885/76/4/046603.
15. Koleske J.V. Paint and Coating Testing Manual (15th Ed.) / J.V. Koleske // ASTM International. – 2012, 880 p.
16. Influence of coalescing agents on waterborne acrylic films / T. Azais et al // Journal of Coatings Technology and Research. – 2015. – № 12(2). – Р. 265-273. https://doi.org/10.1007/s11998-014-9637-2.
17. Self-film-forming waterborne polymers: recent developments / Y. Xiang et al // Progress in Organic Coatings. – 2022. – № 163. – Р. 106654. https://doi.org/10.1016/j.porgcoat.2021.106654.
18. Crosslinked Polymer Coatings of Poly (Acrylic Acid-co-acrylamide)/Polyethyleneimine (P(AAco-AAm)/PEI) on Titanium Alloy with Excellent Lubrication Performance for Artificial Joints / Y. Deng et al // Coatings. – 2024. – № 14(1). – 28. https://doi.org/10.3390/coatings14010028.
19. Mooney Controlling Mechanical and Swelling Properties of Alginate Hydrogels Independently by Cross-Linker Type and Cross-Linking Density / Kuen Yong Lee et al // Macromolecules. – 2000. – № 33(11). – Р. 4291-4294. https://pubs.acs.org/doi/10.1021/ma9921347?ref=recommended.
20. Smart Polymer Nanoparticles for High-Performance Water-Borne Coatings / S. Piçarra et al // Langmuir. – 2014. – № 30(41). – Р. 12345-12353. https://doi.org/10.1021/la502826r.
21. Molecular design and copolymerization to enhance the anti–corrosion performance of waterborne acrylic coatings / J. Sha et al // Progress in Organic Coatings. – 2021. – № 153. – Р. 106140. https://doi.org/10.1016/j.porgcoat.2021.106140.
22. Feasible estimation of weathering stability for free film acrylic coatings via dynamic mechanical analysis as the sole characterization method / F. Steinberger et al // Journal of Coatings Technology and Research. – 2025. – Vol. 22. – P. 839-848. https://doi.org/10.1007/s11998-024-01013-3.
23. Artificial Weathering Test Methods of Waterborne Acrylic Coatings for Steel Structure Corrosion Protection / Ł. Ładosz et al // Materials (Basel). – 2024. – № 17(8). – Р. 1857. https://doi.org/10.3390/ma17081857.
24. Advances in Waterborne Acrylic Resins: Synthesis Principle, Modification Strategies, and Their Applications / C. Jiao et al // ACS Omega. – 2021. https://doi.org/10.1021/acsomega.0c05593.
25. Enhancement of the properties of acrylic wood coatings by modifying them with biopolymers / P. Hochmańska-Kaniewska et al // Progress in Organic Coatings. – 2022.
26. Corrosion protective properties of cellulose nanocrystals reinforced waterborne acrylate-based coating / Y. He et al // Corrosion Science. – 2019.
27. Mazurin O.V. Khimiya i tekhnologiya lakokrasochnykh materialov / O.V. Mazurin, A.I. Ivanov. – Khimiya, Moscow, 2009, 368 p. (In Russian).
28. Kuznetsov I.F. Dobavki i napolniteli v lakokrasochnykh materialakh / I.F. Kuznetsov. – Profi, Saint Petersburg, 2013. – 312 p. (In Russian).
29. Tracton A.A. Coatings Technology Handbook / A.A. Tracton. – 3rd ed. CRC Press, 2005. – 936 p.
30. Wicks Z.W. Organic Coatings: Science and Technology / Z.W. Wicks, F.N. Jones, S.P. Pappas. – 3rd ed. Wiley-Interscience, 2007. – 500 p.
31. Meuler A.J. Block polymers: Past, present, and future / A.J. Meuler, M.A. Hillmyer, F.S. Bates // Macromolecules. – 2009. – № 42(19). – Р. 7221-7250. https://doi.org/10.1021/ma901138u.
32. Alegre R. Incorporation of biopolymers into waterborne acrylic latexes: synthetic strategies and material properties / R. Alegre, C. Prieto, T. Vicent // Polymers. – 2023. – № 17(8). – Р. 1027. https://doi.org/10.3390/polym17081027.
33. Application of chitosan–lignosulfonate composite coating film in food packaging: Improved water, oil and stain resistance / N. Zhang et al // Coatings. – 2022. – № 12(4). – Р. 494. https://doi.org/10.3390/coatings12040494.
34. Mittal K.L. (Ed.). Polymer Surface Modification: Relevance to Adhesion / K.L. Mittal. – CRC Press, 2009. – 408 p.
35. Yurasov S.Yu. Fiziko-khimicheskie osnovy adgezii i stsepleniya pokrytiy. Politekhnika / S.Yu. Yurasov, A.Yu. Blinov // Saint Petersburg, 2011. – 244 p. (In Russian).
36. A bio-based coalescent for improving latex film quality and paint performance / S. Pereira et al // Paint & Coatings Industry. – 2023. Р. 40-43. https://doi.org/10.1016/j.porgcoat.2006.01.006.
37. Waterborne acrylic/casein hybrid latexes with high solids content and reduced coalescent requirement / X. Guo et al // Journal of Coatings Science and Technology. – 2015. – № 35(10). – Р. 1234-1242. https://doi.org/10.1520/MNL6-2015-1010.
38. Saini S. Recent advances in the use of cellulose and its derivatives for sustainable coatings / S. Saini, M.N. Belgacem // Progress in Organic Coatings. – 2020. – № 142. – 105557. https://doi.org/10.1016/j.porgcoat.2019.105557.
39. Rinaudo M. Chitin and chitosan: Properties and applications / M.Rinaudo // Progress in Polymer Science. – 2006. – № 31. – Р. 603-632. https://doi.org/10.1016/j.progpolymsci.2006.06.001.
40. Polymer nanocomposites as efficient materials for coatings: A review / C. Vasile et al // Coatings. – 2020. – № 10(3). – Р. 223. https://doi.org/10.3390/coatings10030223.
41. Photocatalytic coatings based on TiO₂ for self-cleaning applications / H. Zhang et al // Surface & Coatings Technology. – 2016. – № 291. – Р. 64-74. https://doi.org/10.1016/j.surfcoat.2016.02.107.
42. Functional coatings with ZnO nanoparticles: Antibacterial and UV-blocking properties / D. Dutta et al // Journal of Coatings Technology and Research. – 2018. – № 15. – Р. 987-997. https://doi.org/10.1007/s11998-018-0073-2.
43. Khaylen V. Dobavki dlya vodorastvorimykh LKM / V. Khaylen, 2011. – 176 p. (In Russian).
44. An overview of polymer latex film formation and properties / D. Scott et al // Progress in Organic Coatings. – 1999. – № 35(2-3). – Р. 89-99. https://doi.org/10.1016/S0300-9440(99)00037-8.
45. Glass J.E. Surfactant-Modified, Water-Soluble Polymers / J.E. Glass // Journal of Coatings Technology. – 2001. – № 73(922). – Р. 79-89. https://doi.org/10.1007/BF02698218.
46. Miniemulsion polymerization and polymer nanoparticles / F.J. Schork et al //Journal of Controlled Release. – 2005. – № 100(1). – № 1–14. https://doi.org/10.1016/j.jconrel.2004.08.011.
47. De Bruyn P.L. Polymer heterogeneity in waterborne coatings: relationships between morphology and performance / P.L. De Bruyn, A.E. Smith // Journal of Coatings Technology and Research. – № 2009. – № 6(3). – Р. 299-312. https://doi.org/10.1007/s11998-009-9201-5.
48. Croll S.G. Heat and mass transfer in latex paints during drying / S.G. Croll // Journal of Coatings Technology. – 1987. – № 59(751). – Р. 81-92. http://pascalfrancis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7449955.
49. Borden M.V. Self‑warning and self‑repairing mechanisms in functional coatings / M.V Borden, S. Goswami, D. Rankowski // Advanced Materials. – 2024. – № 36. – Р. 2400466. https://doi.org/10.1002/EXP.20240066.
50. Smith J.R. Nanomaterial‑advanced smart coatings: emerging trends shaping the field / J.R. Smith, D.H. Lee // Materials Today Advances. – 2024. – № 15. – 100345. https://doi.org/10.1016/j.mtadv.2024.100345.
51. Surface-active silicone materials in coatings applications / T. Brixner et al // Progress in Organic Coatings. – 2020. – № 142. – Р. 105568. https://doi.org/10.1016/j.porgcoat.2020.105568.
52. Pickering Emulsion and Derived Materials / T.N. Ngai, S. Fujii (eds.). – Springer. – 2017. – 152 p. https://doi.org/10.3390/books978-3-03842-353-9.
53. Stimuli-responsive polymer coatings: recent developments, challenges, and future perspectives / Y. Liu et al // Chemical Society Reviews. – 2021. – № 50. – Р. 12183-12214. https://doi.org/10.1039/D0CS00786J.
54. Stimuli-responsive polymer coatings for controlled-release and sensor applications / L.M. Geever et al // Progress in Organic Coatings. – 2012. – № 74(1). – Р. 91-101. https://doi.org/10.1016/j.porgcoat.2011.11.007.
55. Lakshmi S. A review on phase‑inversion technique‑based polymer microsphere fabrication / S. Lakshmi, R. Castro‑Muñoz, A. Figoli // Colloids and Interface Science Communications. – 2020. – № 39. – Р. 100329. https://doi.org/10.1016/j.colcom.2020.100329.
56. Kranz W.B. The mechanism of phase inversion membrane formation / W.B. Kranz, A.R. Greenberg // Desalination. – 1977. – № 22. – Р. 245-262.
57. Miniemulsion polymerization and polymer nanoparticles / F.J. Schork et al // Journal of Controlled Release. – 2005. – № 100(1). – Р. 1*14. https://doi.org/10.1016/j.jconrel.2004.08.011.
58. Urban D. Polymer Dispersions and Their Industrial Applications / D. Urban, K. Takamura // Wiley-VCH, 2002. – 378 p.
59. Latex film formation: Scientific principles and their application / M.A. Winnik et al // Progress in Organic Coatings. – 2006. – № 55. – Р. 161-168. https://doi.org/10.1016/j.porgcoat.2006.01.006.
60. Landfester K. Miniemulsion polymerization and the structure of polymer and hybrid nanoparticles / K. Landfester // Angewandte Chemie International Edition. – 2009. – № 48(25). – Р. 4488-4507. https://doi.org/10.1002/anie.200805719.
61. Binks B.P. Colloidal Particles at Liquid Interfaces / B.P. Binks, T.S. Horozov // Cambridge University Press, 2006. – 536 p.
62. Keddie J.L. Film formation of latex / J.L. Keddie // Materials Science and Engineering: R: Reports. – 1997. – № 21(3). – Р. 101*170. https://doi.org/10.1016/S0927-796X(97)00009-8.
Review
For citations:
Ostrovnaya D.Yu., Dyuryagina A.N., Byzova Yu.S. MODERN APPROACHES TO THE USE OF MODIFIERS IN WATER-ACRYLIC FILM-FORMING SYSTEMS. Bulletin of Shakarim University. Technical Sciences. 2026;1(1(21)):646-655. https://doi.org/10.53360/2788-7995-2026-1(21)-70
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