ЧЕРНАЯ СМОРОДИНА (RIBES NIGRUM) ИЗ ЗАПАДНОГО КАЗАХСТАНА – НОВЫЙ ПРИРОДНЫЙ ЭКОЛОГИЧЕСКИ ЧИСТЫЙ ИНГИБИТОР КОРРОЗИИ УГЛЕРОДИСТОЙ СТАЛИ

В настоящем исследовании метод потери массы и электрохимические методы были использованы для изучения ингибирующих свойств водного экстракта листьев Ribes nigrum относительно коррозии углеродистой стали в солянокислой среде. Установлено, что в 1,0 моль·дм^-3 HCl эффективность ингибирования экстрактом может достигать 92,66%. Показано, что защитная способность ингибитора возрастает с увеличением его концентрации. Обнаружено, что высокая эффективность ингибирования является результатом самопроизвольной физиосорбции ингибитора (ΔG⁰abs ˃ -20 кДж·моль^-1) на поверхности углеродистой стали, которая подчиняптся модели Ленгмюра. Анализ поляризационных кривых выявил смешанный тип ингибирующего действия исследуемого экстракта, при этом наибольшая эффективность ингибирования достигается при концентрации ингибитора 2,0 г·дм^-3. Электрохимические и гравиметрические данные оказались в хорошем согласии. На основании УФ-спектрофотометрического анализа коррозионной среды до и после погружения образца углеродистой стали, сделано предположение о том, что ингибирующее действие экстракта обусловлено адсорбцией фенольных соединений. Водный экстракт листьев R. nigrum был предложен в качестве недорогого, экологически чистого и эффективного ингибитора коррозии.

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