kaz44Вестник Университета Шакарима. Серия технические наукиBulletin of Shakarim University. Technical Sciences2788-79953006-0524«Шәкәрім университеті» КеАҚ10.53360/2788-7995-2024-2(14)-56kaz44-707Research ArticleХИМИЧЕСКАЯ ТЕХНОЛОГИЯ (ОРИГИНАЛЬНАЯ СТАТЬЯ)CHEMICAL TECHNOLOGY (ORIGINAL ARTICLE)ФИЗИЧЕСКИЕ ЗАКОНОМЕРНОСТИ ПОЛУЧЕНИЯ WN/ZrN КОМПОЗИТНЫХ ПОКРЫТИЙ МЕТОДОМ ВАКУУМНОГО ДУГОВОГО ОСАЖДЕНИЯPHYSICAL PATTERNS OF OBTAINING WN/ZrN COMPOSITE COATINGS BY THE METHOD OF VACUUM ARC DEPOSITIONhttps://orcid.org/0009-0003-6588-8098КасымбаевА.KasymbaevA.

Алексей Касымбаев – докторант 

ResearcherID FCC-1652-2022, Scopus Author ID 57424022400

 070004, Республика Казахстан, г. Усть-Каменогорск, ул. Протозанова 69 

Alexey Kasymbaev – PhD student 

070004, Republic of Kazakhstan, Ust-Kamenogorsk, Protozanova 69 st. 

alexey_kasymbayev@mail.ruhttps://orcid.org/0000-0001-8993-996XСмирноваК.SmirnovaK.

Катерина Смирнова – докторант, кафедра наноэлектроники и модификации поверхности 

 40007, Украина, г. Сумы ул. Римского-Корсакова 2.

Katerina Smirnova – Ph.D. student, Department of  Nanoelectronics and Surface Modification 

 40007, Ukraine, Sumy, 2 Rimsky-Korsakov st. 

alexp@i.uahttps://orcid.org/0000-0002-9218-6492ПогребнякА.PogrebnyakA.

Александр Дмитриевич Погребняк – доктор физико-математических наук, заведующий кафедрой наноэлектроники и модификации поверхности 

40007, Украина, г. Сумы ул. Римского-Корсакова 2

Alexander Dmitrievich Pogrebnyak – Doctor of Physical and Mathematical Sciences, Head of the Department of Nanoelectronics and Surface Modification 

 40007, Ukraine, Sumy, 2 Rimsky-Korsakov st. 

alexp@i.uaВосточно-Казахстанский технический университет им. Д. СерикбаеваКазахстанD. Serikbaev East Kazakhstan Technical UniversityKazakhstanСумской государственный университетУкраинаSumy State UniversityUkraine20242906202412(14)462470Copyright © Касымбаев А., Смирнова К., Погребняк А., 20242024Касымбаев А., Смирнова К., Погребняк А.Kasymbaev A., Smirnova K., Pogrebnyak A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://tech.vestnik.shakarim.kz/jour/article/view/707

Из-за возросших требований к инструментам, используемым в экстремальных условиях эксплуатации продления срока службы инструментов, широко используются защитные покрытия. В данной работе исследуются физические закономерности получения покрытий MeN (Me = Zr, Cr, Mo, Nb) многослойных нанокомпозитов на основе WN, а также влияние на микроструктуру, фазовый состав, а также механические и трибологические свойства. Многослойные покрытия WN/MoN являются новой сферой применения, и для производства этих покрытий впервые используется катодно-дуговое физическое осаждение из паровой фазы (CA-PVD). Кроме того, проводятся расчеты из первых принципов для лучшего понимания свойств осажденных мультислоев. Наблюдаются две микроструктуры покрытия с различными типами решетки: (i) гранецентрированная кубическая и (ii) комбинация гексагональной и ГЦК. Среди исследованных систем WN/NbN демонстрирует превосходные свойства, включая самую низкую удельную скорость изнашивания (1,7 × 10-6 мм3/Нм), высокую твердость и заметный индекс пластичности. Отличные трибологические характеристики можно объяснить такими факторами, как низкая шероховатость поверхности, высокая упругая деформация до разрушения, образование трибопленок Nb2O5 и WO3 во время скольжения, пластичное поведение NbN и структура нанокомпозита.

Due to the increased demands on tools used in extreme operating conditions, protective coatings are widely used to extend the service life of tools. This work examines the physical principles of obtaining MeN coatings (Me = Zr, Cr, Mo, Nb) of multilayer nanocomposites based on WN, as well as the effect on the microstructure, phase composition, as well as mechanical and tribological properties. Multilayer WN/MoN coatings are a new field of application, and cathodic arc physical vapor deposition (CA-PVD) is used for the first time to produce these coatings. In addition, first-principles calculations are performed to better understand the properties of the deposited multilayers. Two coating microstructures with different lattice types are observed: (i) face-centered cubic and (ii) a combination of hexagonal and fcc. Among the systems studied, WN/NbN exhibits superior properties, including the lowest specific wear rate (1.7 × 10-6 mm3/Nm), highhardness, and a remarkable ductility index. The excellent tribological performance can be attributed to factors such as low surface roughness, high elastic strain before failure, formation of Nb2O5 and WO3 tribofilms during sliding, ductile behavior of NbN, and nanocomposite structure.

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The authors declare that there are no conflicts of interest present.