kaz44Вестник Университета Шакарима. Серия технические наукиBulletin of Shakarim University. Technical Sciences2788-79953006-0524«Шәкәрім университеті» КеАҚ10.53360/2788-7995-2026-2(22)-68kaz44-2587Research ArticleХИМИЧЕСКАЯ ТЕХНОЛОГИЯАДСОРБЕНТЫ НА ОСНОВЕ МОДИФИЦИРОВАННОЙ НАНОЦЕЛЛЮЛОЗЫ: ОЧИСТКА ВОДЫ ОТ ОРГАНИЧЕСКИХ И НЕОРГАНИЧЕСКИХ ЗАГРЯЗНИТЕЛЕЙADSORBENTS BASED ON MODIFIED NANOCELLULOSE: WATER PURIFICATION FROM ORGANIC AND INORGANIC POLLUTANTShttps://orcid.org/0000-0003-4131-0905ТоктарбайЖ.ToktarbayZh.

Жексенбек Токтарбай – PhD, ассоц.профессор, научный сотрудник лаборатории инженерного профиля, 

050000, г. Алматы, ул. Сатпаева, 22

Zhexenbek Toktarbay – PhD, Associate Professor, Researcher at the Engineering Profile Laboratory,

050000, Almaty, 22 Satpayev St.

zhexenbek.toktarbay@gmail.comhttps://orcid.org/0000-0002-8640-0667КунарбековаМ. С.KunarbekovaM. S.

Махаббат Сейт-Задаевна Кунарбекова – доктор философии, научный сотрудник лаборатории инженерного профиля, 

050000, г. Алматы, ул. Сатпаева, 22

Makhabbat Kunarbekova – PhD, researcher at the Engineering Laboratory,

050000, Almaty, 22 Satpayev St.

m.kunarbekova@satbayev.universityhttps://orcid.org/0000-0002-7433-1094РахимоваБ. У.RakhimovaB. U.

Бибигул Уалиевна Рахимова ‒ PhD доктор, преподаватель,

050000, г. Алматы, ул. Гоголя, 114/8

Bibigul Ualieva Rakhimova ‒ PhD, Lecturer at the Kazakh national women's teacher training university,

050000, Almaty, 114/8 Gogol St.

bibaarai1976@gmail.comhttps://orcid.org/0000-0002-5444-0314КудайбергеновК. К.KudaibergenovK. K.

Кенес Какимович Кудайбергенов – PhD доктор, Ассоциированный профессор,

050000, г. Алматы, ул. Сатпаева, 22

Кenes Kakimovich Kudaibergenov – PhD, Associate Professor,

050000, Almaty, 22 Satpayev St.

k.kudaibergenov@satbayev.universityhttps://orcid.org/0009-0000-7190-2819АширалиеваД. Н.AshiralievaD. N.

Дана Нурланқызы Аширалиева – магистрант кафедры «Материаловедение, нанотехнология и инженерная физика»,

050000, г. Алматы, ул. Сатпаева, 22

Ashiraliyeva Dana – Master's student of the Department of «Materials Science, Nanotechnology and Engineering Physics»,

050000, Almaty, 22 Satpayev St.

asiralievadana@gmail.comКазахский национальный исследовательский технический университет им. К.И. СатпаеваКазахстанSatbayev University (Kazakh National Research Technical University named after K.I. Satpayev)KazakhstanКазахский национальный женский педагогический университетКазахстанKazakh National Women's Teacher Training UniversityKazakhstan20262907202602(22)648673Copyright © Токтарбай Ж., Кунарбекова М.С., Рахимова Б.У., Кудайбергенов К.К., Аширалиева Д.Н., 20262026Токтарбай Ж., Кунарбекова М.С., Рахимова Б.У., Кудайбергенов К.К., Аширалиева Д.Н.Toktarbay Z., Kunarbekova M.S., Rakhimova B.U., Kudaibergenov K.K., Ashiralieva D.N.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://tech.vestnik.shakarim.kz/jour/article/view/2587

В условиях интенсивного развития промышленности загрязнение водных ресурсов превратилось в глобальную экологическую проблему. В настоящей обзорной статье систематически проанализирована эффективность функционализированных адсорбентов на основе наноцеллюлозы для удаления из воды органических (синтетические красители, фенолы, антибиотики, пестициды) и (Pb2+, Cd2+, Hg2+, Cr(VI), Cu2+, As) загрязнителей. Ключевые результаты: наивысшая сорбционная ёмкость достигается на TEMPO-окисленной наноцеллюлозе и аминфункционализированных композитах – до 2500 мг/г для метиленового синего и до 2270 мг/г для ионов свинца. Молекулярно импринтированные полимеры (МИП) на основе наноцеллюлозы селективно адсорбируют фенолы с эффективностью до 97% даже в присутствии структурно близких конкурентов. Большинство рассмотренных адсорбентов сохраняют 80-90% ёмкости после 20 циклов регенерации. В работе рассмотрены три основных типа наноцеллюлозы (ЦНК, НФЦ, БНЦ), методы их получения (кислотный гидролиз, TEMPO-окисление, механическая и ферментативная обработка) и стратегии поверхностной функционализации (изоцианатная, амини тиольная). Особо отмечается соответствие производства наноцеллюлозы из сельскохозяйственных отходов (рисовая шелуха, соевая шелуха) принципам устойчивого развития. Также определены нерешённые проблемы – масштабирование, стабильность в реальных сточных водах, экономическая эффективность – и перспективные направления исследований.

Against the backdrop of rapid industrial growth, water pollution has become a pressing global environmental issue. This review provides a systematic analysis of the efficiency of functionalized nanocellulose- based adsorbents for the removal of organic (synthetic dyes, phenols, antibiotics, pesticides) and inorganic (Pb2+, Cd2+, Hg2+, Cr(VI), Cu2+, As) pollutants from water. Key findings: the highest sorption capacities are achieved by TEMPO- oxidized nanocellulose and amine-functionalized composites – up to 2500 mg/g for methylene blue and up to 2270 mg/g for lead ions. Nanocellulose- based molecularly imprinted polymers (MIPs) selectively adsorb phenols with efficiencies of up to 97% even in the presence of structurally similar competitors. Most adsorbents reviewed retain 80+90% of their capacity after 20 regeneration cycles. The paper examines three main types of nanocellulose (CNC, NFC, BNC), their preparation methods (acid hydrolysis, TEMPO-oxidation, mechanical and enzymatic treatment), and surface functionalization strategies (isocyanate-based, amine- and thiol-functionalization). The alignment of nanocellulose production from agricultural waste (rice husks, soybean hulls) with sustainable development principles is emphasized. Key unresolved challenges – scale-up, stability in real wastewater matrices, and cost-effectiveness – and future research directions are also identified.

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The authors declare that there are no conflicts of interest present.