kaz44Вестник Университета Шакарима. Серия технические наукиBulletin of Shakarim University. Technical Sciences2788-79953006-0524«Шәкәрім университеті» КеАҚ10.53360/2788-7995-2026-2(22)-65kaz44-2418Research ArticleХИМИЧЕСКАЯ ТЕХНОЛОГИЯМОДИФИЦИРОВАНИЕ ПЛЕНКООБРАЗУЮЩИХ ДЛЯ ЛАКОКРАСОЧНЫХ КОМПОЗИТОВ НА ВОДНОЙ ОСНОВЕMODIFICATION OF FILM-FORMING MATERIALS FOR WATER-BASED PAINT AND VARNISH COMPOSITEShttps://orcid.org/0000-0002-9109-8159ДюрягинаА. Н.DyuryaginaA. N.

Антонина Николаевна Дюрягина – кандидат химических наук., профессор кафедры «Химия и химические технологии», 

150000, г. Петропавловск, ул. Пушкина, 86

Antonina Dyuryagina – candidate of chemical sciences, professor of the department «Chemistry and Chemical Technologies», 

150000, Petropavlovsk, Pushkin str., 86

adyuryagina@inbox.ruhttps://orcid.org/0000-0002-1639-0045ШиринаТ. В.ShirinaT. V.

Татьяна Валерьевна Ширина – докторант кафедры «Химия и химические технологии»,

150000, г. Петропавловск, ул. Пушкина, 86

Tatyana Shirina – doctoral student of the department «Chemistry and Chemical Technologies», 

150000, Petropavlovsk, Pushkin str., 86

tshirina@internet.ruБызоваЮ. С.ByzovaYu. S.

Юлия Сергеевна Бызова – PhD, ассоциированный профессор кафедры «Химия и химические технологии»,

150000, г. Петропавловск, ул. Пушкина, 86

Yuliya Byzova – PhD, associate professor of the department «Chemistry and Chemical Technologies», 

150000, Petropavlovsk, Pushkin str., 86

yuliyabyzovva@gmail.comhttps://orcid.org/0000-0002-8047-5916ЛуценкоА. А.LutsenkoA. A.

Аида Александровна Луценко – PhD, директор отдела коммерциализации,

020000, г. Кокшетау, ул. Ауэзова, 189а

Aida Lutsenko – PhD, director of the commercialization department, 

020000, Kokshetau, Auezova str. 189a 

l-a.13@gmail.comСеверо-Казахстанский университет им. Манаша КозыбаеваКазахстанManash Kozybayev North Kazakhstan UniversityKazakhstanКокшетауский университет имени Абая МырзахметоваКазахстанAbay Myrzakhmetov Kokshetau UniversityKazakhstan20262907202602(22)614628Copyright © Дюрягина А.Н., Ширина Т.В., Бызова Ю.С., Луценко А.А., 20262026Дюрягина А.Н., Ширина Т.В., Бызова Ю.С., Луценко А.А.Dyuryagina A.N., Shirina T.V., Byzova Y.S., Lutsenko A.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://tech.vestnik.shakarim.kz/jour/article/view/2418

Лакокрасочные композиты на водной основе находят все большее применение в строительстве, промышленности и быту. Это обусловлено прежде всего экологическими (снижение эмиссии органических растворителей) и экономическими (вода дешевле и доступнее, чем органические растворители) причинами. Вместе с тем ключевой задачей остаётся повышение барьерных и механических характеристик водных покрытий при сохранении технологичности нанесения и быстрого отверждения. Применяются два основных подхода к модификации водоразбавляемых систем – химическая модификация полимерных связующих и блендирование полимеров. Показано, что целенаправленное варьирование структуры мягких/жёстких сегментов полиуретана, а также введение акрилатной компоненты и функциональных добавок (пластификаторов, нанонаполнителей) позволяет управлять степенью сшивки и фазовым распределением, тем самым повышая адгезию, износостойкость и барьерные свойства покрытий. Среди модифицированных водоразбавляемых систем особый интерес представляют полиуретановые и акрил-полиуретановые покрытия, которые были рассмотрены в статье благодаря уникальному сочетанию их свойств. Эти системы обеспечивают высокую долговечность покрытий и широкую сферу применения, включая защитные и декоративные покрытия для различных материалов. Особое внимание уделено способам их модификации. Отмечена перспективность полиуретановых и акрил-полиуретановых водоразбавляемых покрытий для антикоррозионной защиты и необходимость подбора составов с учётом условий эксплуатации.

Waterborne paint and coating composites are finding increasingly broad application in construction, industry, and everyday use. This shift is largely motivated by environmental goals – lowering organic solvent emissions – and by cost advantages, since water is both less expensive and more widely available than organic solvents.At the same time, the key task remains to increase the barrier and mechanical characteristics of water-based coatings while maintaining the processability of application and rapid curing.Two main approaches are employed to modify water-dispersible systems: chemical modification of polymer binders and polymer blending. It has been shown that targeted tailoring of the polyurethane soft/hard segment structure, as well as the incorporation of an acrylate component and functional additives (plasticizers, nanofillers), enables control over the degree of crosslinking and phase distribution, thereby improving coating adhesion, abrasion resistance, and barrier properties. Among modified waterborne systems, polyurethane and acrylic-polyurethane coatings are of particular interest, as discussed in this article, owing to their unique combination of properties. These systems provide high coating durability and a wide range of applications, including protective and decorative coatings for various substrates. Special attention is given to methods for their modification. The promise of polyurethane and acrylic-polyurethane waterborne coatings for anticorrosion protection is highlighted, along with the need to tailor formulations to specific service conditions.

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The authors declare that there are no conflicts of interest present.