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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">kaz44</journal-id><journal-title-group><journal-title xml:lang="ru">Вестник Университета Шакарима. Серия технические науки</journal-title><trans-title-group xml:lang="en"><trans-title>Bulletin of Shakarim University. Technical Sciences</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2788-7995</issn><issn pub-type="epub">3006-0524</issn><publisher><publisher-name>«Шәкәрім университеті» КеАҚ</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.53360/2788-7995-2025-4(20)-76</article-id><article-id custom-type="elpub" pub-id-type="custom">kaz44-2242</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ХИМИЧЕСКАЯ ТЕХНОЛОГИЯ (ОРИГИНАЛЬНАЯ СТАТЬЯ)</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CHEMICAL TECHNOLOGY (ORIGINAL ARTICLE)</subject></subj-group></article-categories><title-group><article-title>ГЕОПОЛИМЕРЫ НА ОСНОВЕ АЛЮМОСИЛИКАТНОГО СЫРЬЯ: МЕХАНИЗМЫ, СЫРЬЕВЫЕ ИСТОЧНИКИ И ПЕРСПЕКТИВЫ ПРИМЕНЕНИЯ</article-title><trans-title-group xml:lang="en"><trans-title>GEOPOLYMERS BASED ON ALUMINOSILICATE RAW MATERIALS: MECHANISMS, RAW MATERIAL SOURCES AND APPLICATION PROSPECTS</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-5554-1061</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Ғылымханов</surname><given-names>Б. Т.</given-names></name><name name-style="western" xml:lang="en"><surname>Gylymkhanov</surname><given-names>B.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Бекболат Талғатұлы Ғылымханов – докторант кафедры «Химические процессы и промышленная экология»</p><p>050012, Республика Казахстан, г.Алматы, ул. Сатпаева 22</p></bio><bio xml:lang="en"><p>Bekbolat Gylymkhanov – Doctoral student, Department of Chemical Processes and Industrial Ecology</p><p>050012, Republic of Kazakhstan, Almaty, 22 Satbayev Street </p></bio><email xlink:type="simple">bbekaa23@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-7154-9370</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кожанова</surname><given-names>А. Ж.</given-names></name><name name-style="western" xml:lang="en"><surname>Kozhanova</surname><given-names>A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Акерке Жаркыновна Кожанова – магистрант кафедры «Химическая и биохимическая инженерия»</p><p>050012, Республика Казахстан, г.Алматы, ул. Сатпаева 22</p></bio><bio xml:lang="en"><p>Akerke Kozhanova – Master’s student, Department of Chemical and Biochemical Engineering</p><p>050012, Republic of Kazakhstan, Almaty, 22 Satbayev Street</p></bio><email xlink:type="simple">kozhanova250802@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-7721-6473</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Амитова</surname><given-names>А. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Amitova</surname><given-names>A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Айгуль Амантаевна Амитова – PhD, исследователь, научный руководитель проекта кафедры «Химическая и биохимическая инженерия»</p><p>050012, Республика Казахстан, г.Алматы, ул. Сатпаева 22</p></bio><bio xml:lang="en"><p>Aigul Amitova – PhD, Researcher, Project Supervisor, Department of Chemical and Biochemical Engineering</p><p>050012, Republic of Kazakhstan, Almaty, 22 Satbayev Street</p></bio><email xlink:type="simple">aikkash@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-6209-5215</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Елубай</surname><given-names>М. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Yelubay</surname><given-names>M.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Мәдениет Азаматұлы Елубай – кандидат химических наук, декан факультета естественных наук, профессор</p><p>140000, Республика Казахстан, г. Павлодар, ул. Ломова 64</p></bio><bio xml:lang="en"><p>Madeniet Yelubay – Candidate of Chemical Sciences, Dean of the Faculty of Natural Sciences, Professor</p><p>140000, Republic of Kazakhstan, Pavlodar, 64 Lomov Street</p></bio><email xlink:type="simple">yelubay.m@tou.edu.kz</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-9872-6317</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Айткалиева</surname><given-names>Г. С.</given-names></name><name name-style="western" xml:lang="en"><surname>Aitkaliyeva</surname><given-names>G.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Гульзат Сляшевна Айткалиева – PhD, ассоциированный профессор кафедры «Химическая и биохимическая инженерия»</p><p>050012, Республика Казахстан, г.Алматы, ул. Сатпаева 22</p></bio><bio xml:lang="en"><p>Gulzat Aitkaliyeva – PhD, Associate Professor, Department of Chemical and Biochemical Engineering</p><p>050012, Republic of Kazakhstan, Almaty, 22 Satbayev Street</p></bio><email xlink:type="simple">g.aitkaliyeva@satbayev.university</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru">Казахский национальный исследовательский технический университет имени К.И. Сатпаева<country>Казахстан</country></aff><aff xml:lang="en">Satbayev University<country>Kazakhstan</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru">Торайгыров университет<country>Казахстан</country></aff><aff xml:lang="en">Toraighyrov University<country>Kazakhstan</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2025</year></pub-date><pub-date pub-type="epub"><day>25</day><month>01</month><year>2026</year></pub-date><volume>1</volume><issue>4(20)</issue><fpage>654</fpage><lpage>665</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Ғылымханов Б.Т., Кожанова А.Ж., Амитова А.А., Елубай М.А., Айткалиева Г.С., 2026</copyright-statement><copyright-year>2026</copyright-year><copyright-holder xml:lang="ru">Ғылымханов Б.Т., Кожанова А.Ж., Амитова А.А., Елубай М.А., Айткалиева Г.С.</copyright-holder><copyright-holder xml:lang="en">Gylymkhanov B., Kozhanova A., Amitova A., Yelubay M., Aitkaliyeva G.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://tech.vestnik.shakarim.kz/jour/article/view/2242">https://tech.vestnik.shakarim.kz/jour/article/view/2242</self-uri><abstract><p>В работе рассмотрены современные направления развития геополимерных композитов как экологически устойчивой альтернативы портландцементу. Приведён анализ сырьевых источников для геополимеризации, включая природные алюмосиликатные материалы и техногенные отходы промышленности – золы-уноса, доменные и ферросплавные шлаки, красный шлам и другие побочные продукты энергетического и металлургического производств. Описаны основные стадии и механизмы геополимеризации, влияние щёлочных активаторов и параметров синтеза на формирование структуры и свойства материалов. Показано, что геополимерные композиты обладают высокой прочностью, термостойкостью и химической стойкостью при существенно меньшем углеродном следе, что делает их перспективными для применения в строительстве и утилизации промышленных отходов.Отмечено, что Республика Казахстан располагает значительными запасами как природных алюмосиликатных пород, так и вторичных техногенных ресурсов, что создаёт предпосылки для широкого внедрения геополимерных технологий в целях снижения экологической нагрузки и повышения эффективности использования минерального сырья.</p></abstract><trans-abstract xml:lang="en"><p>The paper discusses current trends in the development of geopolymer composites as an environmentally sustainable alternative to Portland cement. An analysis of raw material sources for geopolymerization is presented, including natural aluminosilicate materials and industrial by-products such as fly ash, blast furnace and ferroalloy slags, red mud, and other residues from energy and metallurgical industries. The main stages and mechanisms of geopolymerization are described, as well as the influence of alkaline activators and synthesis parameters on the formation of the structure and properties of the materials. It is shown that geopolymer composites exhibit high strength, thermal stability, and chemical resistance with a significantly lower carbon footprint, making them promising for use in construction and industrial waste recycling.It is noted that the Republic of Kazakhstan possesses substantial reserves of both natural aluminosilicate rocks and secondary technogenic resources, which creates favorable conditions for the widespread implementation of geopolymer technologies aimed at reducing environmental impact and improving the efficiency of mineral resource utilization.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>геополимер</kwd><kwd>активатор</kwd><kwd>сырье</kwd><kwd>алюмосиликаты</kwd><kwd>зола уноса</kwd><kwd>промышленные отходы</kwd><kwd>шламы</kwd></kwd-group><kwd-group xml:lang="en"><kwd>geopolymer</kwd><kwd>activator</kwd><kwd>raw materials</kwd><kwd>aluminosilicates</kwd><kwd>fly ash</kwd><kwd>industrial waste</kwd><kwd>sludge</kwd></kwd-group><funding-group xml:lang="ru"><funding-statement>Данное исследование финансируется Комитетом науки Министерства науки и высшего образования Республики Казахстан (грант № AP26197535 «Разработка геополимерных композитов на основе металлургических отходов»).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">О внесении изменений и дополнений в Постановление Правительства Республики Казахстан от 30 октября 2010 года № 1144 «Об утверждении Программы по развитию горно-металлургической отрасли в Республике Казахстан на 2010-2014 годы».</mixed-citation><mixed-citation xml:lang="en">О внесении изменений и дополнений в Постановление Правительства Республики Казахстан от 30 октября 2010 года № 1144 «Об утверждении Программы по развитию горно-металлургической отрасли в Республике Казахстан на 2010-2014 годы».</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Chemical fundamentals of geopolymers in sustainable construction / М. Makungu et al // Materials Today Sustainability. – 2024. – Vol. 27. https://doi.org/10.1016/j.mtsust.2024.100842.</mixed-citation><mixed-citation xml:lang="en">Chemical fundamentals of geopolymers in sustainable construction / М. Makungu et al // Materials Today Sustainability. – 2024. – Vol. 27. https://doi.org/10.1016/j.mtsust.2024.100842.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Geopolymers: The green alternative to traditional materials for engineering applications / Z. Jwaidat et al // Infrastructures. – 2023. – № 8. – Р. 98.</mixed-citation><mixed-citation xml:lang="en">Geopolymers: The green alternative to traditional materials for engineering applications / Z. Jwaidat et al // Infrastructures. – 2023. – № 8. – Р. 98.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Tayeh B.A. The utilization of recycled aggregate in high performance concrete: A review / B.A. Tayeh, D.M. Al Saffar, R. Alyousef // Journal of Materials Research and Technology. – 2020. – № 9. – Р. 8469-8481.</mixed-citation><mixed-citation xml:lang="en">Tayeh B.A. The utilization of recycled aggregate in high performance concrete: A review / B.A. Tayeh, D.M. Al Saffar, R. Alyousef // Journal of Materials Research and Technology. – 2020. – № 9. – Р. 8469-8481.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Geopolymer concrete as sustainable material: A state-of-the-art review / F. Farooq et al // Construction and Building Materials. – 2021. – № 306. – Р. 124762.</mixed-citation><mixed-citation xml:lang="en">Geopolymer concrete as sustainable material: A state-of-the-art review / F. Farooq et al // Construction and Building Materials. – 2021. – № 306. – Р. 124762.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Sustainable Geopolymer Tuff Composites Utilizing Iron Powder Waste: Rheological and Mechanical Performance Evaluation / M.L.K. Khouadjia et al // Sustainability. – 2025. – № 17. – Р. 1240. https://doi.org/10.3390/su17031240.</mixed-citation><mixed-citation xml:lang="en">Sustainable Geopolymer Tuff Composites Utilizing Iron Powder Waste: Rheological and Mechanical Performance Evaluation / M.L.K. Khouadjia et al // Sustainability. – 2025. – № 17. – Р. 1240. https://doi.org/10.3390/su17031240.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Review: geopolymers for fire protection applications / R. Mohamed et al // J Mater Sci. – 2025. – № 60. – Р. 18678-18709. https://doi.org/10.1007/s10853-025-11496-z.</mixed-citation><mixed-citation xml:lang="en">Review: geopolymers for fire protection applications / R. Mohamed et al // J Mater Sci. – 2025. – № 60. – Р. 18678-18709. https://doi.org/10.1007/s10853-025-11496-z.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Geopolymer Materials: Cutting-Edge Solutions for Sustainable Design Building / L. Ricciotti et al // Sustainability. – 2025. – № 17. – Р. 7483. https://doi.org/10.3390/su17167483.</mixed-citation><mixed-citation xml:lang="en">Geopolymer Materials: Cutting-Edge Solutions for Sustainable Design Building / L. Ricciotti et al // Sustainability. – 2025. – № 17. – Р. 7483. https://doi.org/10.3390/su17167483.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Ujianto M. Structural Behavior of Precast ConcreteWall Panels Due to Dynamic Load: A Review / M. Ujianto, A.Z. Mohd Ali, M. Solikin // AIP Conf. Proc. – 2019. – № 2114. – Р. 050013.</mixed-citation><mixed-citation xml:lang="en">Ujianto M. Structural Behavior of Precast ConcreteWall Panels Due to Dynamic Load: A Review / M. Ujianto, A.Z. Mohd Ali, M. Solikin // AIP Conf. Proc. – 2019. – № 2114. – Р. 050013.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Dimas D.D. Utilization of alumina red mud for synthesis of inorganic polymeric materials / D.D. Dimas, I.P. Giannopoulou, D. Panias // Miner. Process. Extr. Metall. Rev. – 2009. – № 30. – Р. 211-239.</mixed-citation><mixed-citation xml:lang="en">Dimas D.D. Utilization of alumina red mud for synthesis of inorganic polymeric materials / D.D. Dimas, I.P. Giannopoulou, D. Panias // Miner. Process. Extr. Metall. Rev. – 2009. – № 30. – Р. 211-239.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Nuaklong P. Properties of metakaolin-high calcium fly ash geopolymer concrete containing recycled aggregate from crushed concrete specimens / P. Nuaklong, V. Sata, P. Chindaprasirt // Constr. Build. Mater. – 2018. https://doi.org/10.1016/j.conbuildmat.2017.11.152.</mixed-citation><mixed-citation xml:lang="en">Nuaklong P. Properties of metakaolin-high calcium fly ash geopolymer concrete containing recycled aggregate from crushed concrete specimens / P. Nuaklong, V. Sata, P. Chindaprasirt // Constr. Build. Mater. – 2018. https://doi.org/10.1016/j.conbuildmat.2017.11.152.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Alomayri T. Experimental study of the microstructural and mechanical properties of geopolymer paste with nano material (Al2O3) / T. Alomayri // J. Build. Eng. – 2019. https://doi.org/10.1016/j.jobe.2019.100788.</mixed-citation><mixed-citation xml:lang="en">Alomayri T. Experimental study of the microstructural and mechanical properties of geopolymer paste with nano material (Al2O3) / T. Alomayri // J. Build. Eng. – 2019. https://doi.org/10.1016/j.jobe.2019.100788.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Synthesis and characterization of red mud and rice husk ash-based geopolymer composites / J. He et al // Cem. Concr. Compos. – 2013. – № 37. – Р. 108-118. https://doi.org/10.1016/j.cemconcomp.2012.11.010.</mixed-citation><mixed-citation xml:lang="en">Synthesis and characterization of red mud and rice husk ash-based geopolymer composites / J. He et al // Cem. Concr. Compos. – 2013. – № 37. – Р. 108-118. https://doi.org/10.1016/j.cemconcomp.2012.11.010.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Olive biomass ash as an alternative activator in geopolymer formation: A study of strength, radiology and leaching behavior / M.M. Alonso et al // Cement and Concrete Composites. – 2019. – Vol. 104. https://doi.org/10.1016/j.cemconcomp.2019.103384.</mixed-citation><mixed-citation xml:lang="en">Olive biomass ash as an alternative activator in geopolymer formation: A study of strength, radiology and leaching behavior / M.M. Alonso et al // Cement and Concrete Composites. – 2019. – Vol. 104. https://doi.org/10.1016/j.cemconcomp.2019.103384.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Maaty Al.A. Geopolymer Concrete Performance Utilising Waste Glass: A Review / Al.A. Maaty, M.F. Ghazy, M.G. Eldmarny // Mansoura Engineering Journal. – 2025. – Vol. 50, Iss. 3. https://doi.org/10.58491/2735-4202.3254.</mixed-citation><mixed-citation xml:lang="en">Maaty Al.A. Geopolymer Concrete Performance Utilising Waste Glass: A Review / Al.A. Maaty, M.F. Ghazy, M.G. Eldmarny // Mansoura Engineering Journal. – 2025. – Vol. 50, Iss. 3. https://doi.org/10.58491/2735-4202.3254.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Harnessing waste for sustainable construction: Novel synthesizing activators from waste for geopolymer concrete / Murali G. et al // Theor. Appl. Fract. Mech. – 2024. – №124. – Р. 103559.</mixed-citation><mixed-citation xml:lang="en">Harnessing waste for sustainable construction: Novel synthesizing activators from waste for geopolymer concrete / Murali G. et al // Theor. Appl. Fract. Mech. – 2024. – №124. – Р. 103559.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Properties and performance of fly ash–based geopolymer as concrete repair material / W.W.A. Zailani et al // In Recent Developments of Geopolymer Materials; Woodhead Publishing: Cambridge, UK. – 2025. – Р. 163-179.</mixed-citation><mixed-citation xml:lang="en">Properties and performance of fly ash–based geopolymer as concrete repair material / W.W.A. Zailani et al // In Recent Developments of Geopolymer Materials; Woodhead Publishing: Cambridge, UK. – 2025. – Р. 163-179.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Shafiq M.U. Applications of geopolymers / M.U. Shafiq, M. Jamil, , Khan, M., 2025. // Sustain. Struct. Mater. 256.</mixed-citation><mixed-citation xml:lang="en">Shafiq M.U. Applications of geopolymers / M.U. Shafiq, M. Jamil, , Khan, M., 2025. // Sustain. Struct. Mater. 256.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Smith, J. Sustainable recycling practices for waste glass in construction materials / J. Smith // J. Sustain. Mater. – 2021. – № 12. – Р. 45e54.</mixed-citation><mixed-citation xml:lang="en">Smith, J. Sustainable recycling practices for waste glass in construction materials / J. Smith // J. Sustain. Mater. – 2021. – № 12. – Р. 45e54.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Effect of Aluminium Powder on Kaolin-Based Geopolymer Characteristic and Removal of Cu2+ / N. Ariffin et al // Materials. – 2021. – № 14. – Р. 814.</mixed-citation><mixed-citation xml:lang="en">Effect of Aluminium Powder on Kaolin-Based Geopolymer Characteristic and Removal of Cu2+ / N. Ariffin et al // Materials. – 2021. – № 14. – Р. 814.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Assessment of the Suitability of Ceramic Waste in Geopolymer Composites: An Appraisal / I. Luhar et al // Materials. – 2021. – № 14. – Р. 3279. https://doi.org/10.3390/ma14123279.</mixed-citation><mixed-citation xml:lang="en">Assessment of the Suitability of Ceramic Waste in Geopolymer Composites: An Appraisal / I. Luhar et al // Materials. – 2021. – № 14. – Р. 3279. https://doi.org/10.3390/ma14123279.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">New Blended Cement from Polishing and Glazing Ceramic Sludge / F. Andreola et al // Int. J. Appl. Ceram. Technol. – 2009. – № 7. – Р. 546-555.</mixed-citation><mixed-citation xml:lang="en">New Blended Cement from Polishing and Glazing Ceramic Sludge / F. Andreola et al // Int. J. Appl. Ceram. Technol. – 2009. – № 7. – Р. 546-555.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Study of Novel Geopolymer Concrete Prepared with Slate Stone Cutting Sludge, Chamotte, Steel Slag and Activated with Olive Stone Bottom Ash / R. Carrillo Beltran et al // Materials. – 2025. – № 18. – Р. 1974. https://doi.org/10.3390/ma18091974.</mixed-citation><mixed-citation xml:lang="en">Study of Novel Geopolymer Concrete Prepared with Slate Stone Cutting Sludge, Chamotte, Steel Slag and Activated with Olive Stone Bottom Ash / R. Carrillo Beltran et al // Materials. – 2025. – № 18. – Р. 1974. https://doi.org/10.3390/ma18091974.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Geopolymers: An option for the valorization of incinerator bottom ash derived «end of waste» / Lancellotti I. // Ceramics International. – 2015. – Vol. 41, Issue 2, Part A. – P. 2116-2123. https://doi.org/10.1016/j.ceramint.2014.10.008.</mixed-citation><mixed-citation xml:lang="en">Geopolymers: An option for the valorization of incinerator bottom ash derived «end of waste» / Lancellotti I. // Ceramics International. – 2015. – Vol. 41, Issue 2, Part A. – P. 2116-2123. https://doi.org/10.1016/j.ceramint.2014.10.008.</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Madhuchhanda S. Partial replacement of metakaolin with red ceramic waste in geopolymer / S. Madhuchhanda, D. Kausik // Ceramics International. – 2021. – Vol. 47, Issue 3. – P. 3473-3483. https://doi.org/10.1016/j.ceramint.2020.09.191.</mixed-citation><mixed-citation xml:lang="en">Madhuchhanda S. Partial replacement of metakaolin with red ceramic waste in geopolymer / S. Madhuchhanda, D. Kausik // Ceramics International. – 2021. – Vol. 47, Issue 3. – P. 3473-3483. https://doi.org/10.1016/j.ceramint.2020.09.191.</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">A review on properties of fresh and hardened geopolymer mortar / P. Zhang et al // Composites B: Engineering. – 2018. – № 152. – Р. 79-95.</mixed-citation><mixed-citation xml:lang="en">A review on properties of fresh and hardened geopolymer mortar / P. Zhang et al // Composites B: Engineering. – 2018. – № 152. – Р. 79-95.</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Pacheco-Torgal F. Properties of tungsten mine waste geopolymeric binder / F. Pacheco-Torgal, J. Castro-Gomes, S. Jalali // Construction and Building Materials. – 2008. – № 22. – Р. 1201-1211.</mixed-citation><mixed-citation xml:lang="en">Pacheco-Torgal F. Properties of tungsten mine waste geopolymeric binder / F. Pacheco-Torgal, J. Castro-Gomes, S. Jalali // Construction and Building Materials. – 2008. – № 22. – Р. 1201-1211.</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Compressive strength and microstructural analysis of fly ash/palm oil fuel ash based geopolymer mortar under elevated temperatures / N. Ranjbar et al // Construction and Building Materials. – 2014. – № 65. – Р. 114-121.</mixed-citation><mixed-citation xml:lang="en">Compressive strength and microstructural analysis of fly ash/palm oil fuel ash based geopolymer mortar under elevated temperatures / N. Ranjbar et al // Construction and Building Materials. – 2014. – № 65. – Р. 114-121.</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Effects of Si/Al ratio on the structure and properties of metakaolin based geopolymer / P.G. He et al // Ceram. Int. – 2016. – № 42. – Р. 14416-14422.</mixed-citation><mixed-citation xml:lang="en">Effects of Si/Al ratio on the structure and properties of metakaolin based geopolymer / P.G. He et al // Ceram. Int. – 2016. – № 42. – Р. 14416-14422.</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Role of the silica source on the geopolymerization rate / A. Autef et al // J. Non-Cryst. Solids. – 2012. – № 358. – Р. 2886-2893.</mixed-citation><mixed-citation xml:lang="en">Role of the silica source on the geopolymerization rate / A. Autef et al // J. Non-Cryst. Solids. – 2012. – № 358. – Р. 2886-2893.</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">The composition range of aluminosilicate geopolymers / R.A. Fletcher et al // J. Eur. Ceram. Soc. – 2005. – № 25. – Р. 1471-1477.</mixed-citation><mixed-citation xml:lang="en">The composition range of aluminosilicate geopolymers / R.A. Fletcher et al // J. Eur. Ceram. Soc. – 2005. – № 25. – Р. 1471-1477.</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Optimization of brick waste-based geopolymer binders at ambient temperature and pre-targeted chemical parameters / O. Mahmoodi et al // J. Clean. Prod. – 2020. – № 268. https://doi.org/10.1016/j.jclepro.2020.122285.</mixed-citation><mixed-citation xml:lang="en">Optimization of brick waste-based geopolymer binders at ambient temperature and pre-targeted chemical parameters / O. Mahmoodi et al // J. Clean. Prod. – 2020. – № 268. https://doi.org/10.1016/j.jclepro.2020.122285.</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Influence of calcium aluminate cement (CAC) on alkaline activation of red clay brick waste (RCBW) / L. Reig et al // Cement Concr. Compos. – 2016. – № 65. – Р. 177-185.</mixed-citation><mixed-citation xml:lang="en">Influence of calcium aluminate cement (CAC) on alkaline activation of red clay brick waste (RCBW) / L. Reig et al // Cement Concr. Compos. – 2016. – № 65. – Р. 177-185.</mixed-citation></citation-alternatives></ref><ref id="cit34"><label>34</label><citation-alternatives><mixed-citation xml:lang="ru">Properties and microstructure of alkali-activated red clay brick waste / L. Reig et al // Construct. Build. Mater. – 2013. – № 43. – Р. 98-106.</mixed-citation><mixed-citation xml:lang="en">Properties and microstructure of alkali-activated red clay brick waste / L. Reig et al // Construct. Build. Mater. – 2013. – № 43. – Р. 98-106.</mixed-citation></citation-alternatives></ref><ref id="cit35"><label>35</label><citation-alternatives><mixed-citation xml:lang="ru">Application of waste brick powder in alkali activated aluminosilicates: functional and environmental aspects / J. Fort et al // J. Clean. Prod. – 2018. – № 194. – Р. 714-725.</mixed-citation><mixed-citation xml:lang="en">Application of waste brick powder in alkali activated aluminosilicates: functional and environmental aspects / J. Fort et al // J. Clean. Prod. – 2018. – № 194. – Р. 714-725.</mixed-citation></citation-alternatives></ref><ref id="cit36"><label>36</label><citation-alternatives><mixed-citation xml:lang="ru">Development of high-strength alkali-activated pastes containing high volumes of waste brick and ceramic powders / C.L. Hwang et al // Construct. Build. Mater. – 2019. – № 218. – Р. 519-528.</mixed-citation><mixed-citation xml:lang="en">Development of high-strength alkali-activated pastes containing high volumes of waste brick and ceramic powders / C.L. Hwang et al // Construct. Build. Mater. – 2019. – № 218. – Р. 519-528.</mixed-citation></citation-alternatives></ref><ref id="cit37"><label>37</label><citation-alternatives><mixed-citation xml:lang="ru">Rossignol, Feasibility of producing geopolymer binder based on a brick clay mixture / J. Peyne et al // Ceram. Int. – 2017. – № 43. – Р. 9860-9871.</mixed-citation><mixed-citation xml:lang="en">Rossignol, Feasibility of producing geopolymer binder based on a brick clay mixture / J. Peyne et al // Ceram. Int. – 2017. – № 43. – Р. 9860-9871.</mixed-citation></citation-alternatives></ref><ref id="cit38"><label>38</label><citation-alternatives><mixed-citation xml:lang="ru">US 8 523 998 B2. Process for producing geopolymers / Edgar Gasafi, Katja Dombrowski-Daube. – Publ. – 2013.</mixed-citation><mixed-citation xml:lang="en">US 8 523 998 B2. Process for producing geopolymers / Edgar Gasafi, Katja Dombrowski-Daube. – Publ. – 2013.</mixed-citation></citation-alternatives></ref><ref id="cit39"><label>39</label><citation-alternatives><mixed-citation xml:lang="ru">US 5 342 595 A. Process for obtaining a geopolymericalumino-silicate and products thus obtained / J. Davidovits, M. Davidovics, N. Davidovits. – Publ. – 1994.</mixed-citation><mixed-citation xml:lang="en">US 5 342 595 A. Process for obtaining a geopolymericalumino-silicate and products thus obtained / J. Davidovits, M. Davidovics, N. Davidovits. – Publ. – 1994.</mixed-citation></citation-alternatives></ref><ref id="cit40"><label>40</label><citation-alternatives><mixed-citation xml:lang="ru">EP 4 484 398 A1. Geopolymer compositions comprising aluminum sludge and use thereof / A. Da Silva, A. Bem d’Eça Peixinho, F. Mendes Gaspar, T. Siqueira de Almeida Archer de Carvalho. – Publ. 2023.</mixed-citation><mixed-citation xml:lang="en">EP 4 484 398 A1. Geopolymer compositions comprising aluminum sludge and use thereof / A. Da Silva, A. Bem d’Eça Peixinho, F. Mendes Gaspar, T. Siqueira de Almeida Archer de Carvalho. – Publ. 2023.</mixed-citation></citation-alternatives></ref><ref id="cit41"><label>41</label><citation-alternatives><mixed-citation xml:lang="ru">№ 20220629 A1. One-part geopolymer composition: patent application / Mahmoud Khalifeh, Mohamed Ahmed Fathy Abdelshafy Omran; applicant: Universitetet i Stavanger. – Publ. 2023.</mixed-citation><mixed-citation xml:lang="en">№ 20220629 A1. One-part geopolymer composition: patent application / Mahmoud Khalifeh, Mohamed Ahmed Fathy Abdelshafy Omran; applicant: Universitetet i Stavanger. – Publ. 2023.</mixed-citation></citation-alternatives></ref><ref id="cit42"><label>42</label><citation-alternatives><mixed-citation xml:lang="ru">WO 2015/089611 A1. Geopolymer cement produced from recycled glass and method for producing same: international patent application / Sidnei Antonio Pianaro, Gino Capobianco; applicant: Universidade Estadual de Ponta Grossa. – Publ. 2015.</mixed-citation><mixed-citation xml:lang="en">WO 2015/089611 A1. Geopolymer cement produced from recycled glass and method for producing same: international patent application / Sidnei Antonio Pianaro, Gino Capobianco; applicant: Universidade Estadual de Ponta Grossa. – Publ. 2015.</mixed-citation></citation-alternatives></ref><ref id="cit43"><label>43</label><citation-alternatives><mixed-citation xml:lang="ru">CN 110759655 B. Industrial-waste-based geopolymer : invention patent / Tian Jun, E Xinrui, Wang Deyong, Qu Tianpeng, Shi Jialun, Xiong Yuandong, Lu Shilei, Zhang Min ; applicant: Suzhou University. – Publ. 2021.</mixed-citation><mixed-citation xml:lang="en">CN 110759655 B. Industrial-waste-based geopolymer : invention patent / Tian Jun, E Xinrui, Wang Deyong, Qu Tianpeng, Shi Jialun, Xiong Yuandong, Lu Shilei, Zhang Min ; applicant: Suzhou University. – Publ. 2021.</mixed-citation></citation-alternatives></ref><ref id="cit44"><label>44</label><citation-alternatives><mixed-citation xml:lang="ru">Пат. RU 2503617 C2. Фризон Ф., Жуссо Дюбьен К. Способ получения геополимера с регулируемой пористостью, полученный геополимер и различные варианты его применения. Опубл. 2014.</mixed-citation><mixed-citation xml:lang="en">Пат. RU 2503617 C2. Фризон Ф., Жуссо Дюбьен К. Способ получения геополимера с регулируемой пористостью, полученный геополимер и различные варианты его применения. Опубл. 2014.</mixed-citation></citation-alternatives></ref><ref id="cit45"><label>45</label><citation-alternatives><mixed-citation xml:lang="ru">EA 040554 B1 Кондратович Ф. Л., Утрата К., Микошек-Оперхальская М. Способ получения геополимера или геополимерного композита. Опубл. 2022.</mixed-citation><mixed-citation xml:lang="en">EA 040554 B1 Кондратович Ф. Л., Утрата К., Микошек-Оперхальская М. Способ получения геополимера или геополимерного композита. Опубл. 2022.</mixed-citation></citation-alternatives></ref><ref id="cit46"><label>46</label><citation-alternatives><mixed-citation xml:lang="ru">WO 2015/089611 A1. Cimento geopolimérico a partir de vidros reciclados e seu processo de obtenção / R.H. Santos et al – 2015.</mixed-citation><mixed-citation xml:lang="en">WO 2015/089611 A1. Cimento geopolimérico a partir de vidros reciclados e seu processo de obtenção / R.H. Santos et al – 2015.</mixed-citation></citation-alternatives></ref><ref id="cit47"><label>47</label><citation-alternatives><mixed-citation xml:lang="ru">Radhakrishnan S. Analysis of Ferro-Geopolymer Panels Reinforced with Different Types of Fibres / S. Radhakrishnan, N. Soundarapandian // Struct. Concr. – 2025. – № 26. – Р. 2052-2066.</mixed-citation><mixed-citation xml:lang="en">Radhakrishnan S. Analysis of Ferro-Geopolymer Panels Reinforced with Different Types of Fibres / S. Radhakrishnan, N. Soundarapandian // Struct. Concr. – 2025. – № 26. – Р. 2052-2066.</mixed-citation></citation-alternatives></ref><ref id="cit48"><label>48</label><citation-alternatives><mixed-citation xml:lang="ru">Temuujin J. Preparation and thermal behaviour of potassium aluminosilicate geopolymers / J. Temuujin, A. van Riessen, K.J.D. MacKenzie // J. Non-Cryst. Solids. – 2010. – № 356. – Р. 2023-2027.</mixed-citation><mixed-citation xml:lang="en">Temuujin J. Preparation and thermal behaviour of potassium aluminosilicate geopolymers / J. Temuujin, A. van Riessen, K.J.D. MacKenzie // J. Non-Cryst. Solids. – 2010. – № 356. – Р. 2023-2027.</mixed-citation></citation-alternatives></ref><ref id="cit49"><label>49</label><citation-alternatives><mixed-citation xml:lang="ru">Garcia-Lodeiro I. Variation in hybrid cements over time / I. Garcia-Lodeiro, A. FernandezJimenez, A. Palomo // Cem. Concr. Res. – 2013 – № 52. – Р. 112-122.</mixed-citation><mixed-citation xml:lang="en">Garcia-Lodeiro I. Variation in hybrid cements over time / I. Garcia-Lodeiro, A. FernandezJimenez, A. Palomo // Cem. Concr. Res. – 2013 – № 52. – Р. 112-122.</mixed-citation></citation-alternatives></ref><ref id="cit50"><label>50</label><citation-alternatives><mixed-citation xml:lang="ru">Effect of Silicate Modulus and Metakaolin Incorporation on the Carbonation of Alkali SilicateActivated Slags / S.A. Bernal et al // Cem. Concr. Res. – 2010. – № 40. – Р. 898-907.</mixed-citation><mixed-citation xml:lang="en">Effect of Silicate Modulus and Metakaolin Incorporation on the Carbonation of Alkali SilicateActivated Slags / S.A. Bernal et al // Cem. Concr. Res. – 2010. – № 40. – Р. 898-907.</mixed-citation></citation-alternatives></ref><ref id="cit51"><label>51</label><citation-alternatives><mixed-citation xml:lang="ru">The role of calcium in blended fly ash geopolymers / G.M. Canfield et al // J. Mater. Sci. – 2014. – № 17. – Р. 5922-5933.</mixed-citation><mixed-citation xml:lang="en">The role of calcium in blended fly ash geopolymers / G.M. Canfield et al // J. Mater. Sci. – 2014. – № 17. – Р. 5922-5933.</mixed-citation></citation-alternatives></ref><ref id="cit52"><label>52</label><citation-alternatives><mixed-citation xml:lang="ru">Influence of Activators on Mechanical Properties of Modified Fly Ash Based Geopolymer Mortars / P. Prochon et al // Materials (Basel). – 2020. – № 13(5). – Р. 1033. https://doi.org/10.3390/ma13051033. PMID: 32106414; PMCID: PMC7084247.</mixed-citation><mixed-citation xml:lang="en">Influence of Activators on Mechanical Properties of Modified Fly Ash Based Geopolymer Mortars / P. Prochon et al // Materials (Basel). – 2020. – № 13(5). – Р. 1033. https://doi.org/10.3390/ma13051033. PMID: 32106414; PMCID: PMC7084247.</mixed-citation></citation-alternatives></ref><ref id="cit53"><label>53</label><citation-alternatives><mixed-citation xml:lang="ru">Exemplification of efficacy of homebrewed sodium silicate solution processed from ecoprocessed pozzolan and palm oil clinker powder in geopolymer mortar / H.A.A.E. Ghanim et al // Construction and Building Materials. – 2025. – Vol. 460. https://doi.org/10.1016/j.conbuildmat.2024.139825.</mixed-citation><mixed-citation xml:lang="en">Exemplification of efficacy of homebrewed sodium silicate solution processed from ecoprocessed pozzolan and palm oil clinker powder in geopolymer mortar / H.A.A.E. Ghanim et al // Construction and Building Materials. – 2025. – Vol. 460. https://doi.org/10.1016/j.conbuildmat.2024.139825.</mixed-citation></citation-alternatives></ref><ref id="cit54"><label>54</label><citation-alternatives><mixed-citation xml:lang="ru">Effect of natural and artificial silicon additives on the physicomechanical performance of dolomite-based alkaline-activated mortar / M. Kaya et al // Silicon. – 2024. – № 16(1). – Р. 215-230. https://doi.org/10.1007/s12633-023-02677-z.</mixed-citation><mixed-citation xml:lang="en">Effect of natural and artificial silicon additives on the physicomechanical performance of dolomite-based alkaline-activated mortar / M. Kaya et al // Silicon. – 2024. – № 16(1). – Р. 215-230. https://doi.org/10.1007/s12633-023-02677-z.</mixed-citation></citation-alternatives></ref><ref id="cit55"><label>55</label><citation-alternatives><mixed-citation xml:lang="ru">JProvis.L. Alkali-activated materials / J.L. Provis // Cem. Concr. Res. – 2018. – № 114. – Р. 40-48. https://doi.org/10.1016/j.cemconres.2017.02.009.</mixed-citation><mixed-citation xml:lang="en">JProvis.L. Alkali-activated materials / J.L. Provis // Cem. Concr. Res. – 2018. – № 114. – Р. 40-48. https://doi.org/10.1016/j.cemconres.2017.02.009.</mixed-citation></citation-alternatives></ref><ref id="cit56"><label>56</label><citation-alternatives><mixed-citation xml:lang="ru">Jaarsveld van J. Effect of the Alkali Metal Activator on the Properties of Fly Ash-Based Geopolymers / J. Jaarsveld van, J. Deventer van // Eng. Chem. Res. – 1999. – № 38. – Р. 3932-3941.</mixed-citation><mixed-citation xml:lang="en">Jaarsveld van J. Effect of the Alkali Metal Activator on the Properties of Fly Ash-Based Geopolymers / J. Jaarsveld van, J. Deventer van // Eng. Chem. Res. – 1999. – № 38. – Р. 3932-3941.</mixed-citation></citation-alternatives></ref><ref id="cit57"><label>57</label><citation-alternatives><mixed-citation xml:lang="ru">Fawer M. Life cycle inventories for the production of sodium silicates / M. Fawer, M. Concannon, W. Rieber // Int. J. Life Cycle Assess. – 1999. – № 4(4). – Р. 207-212. https://doi.org/10.1007/BF02979498.</mixed-citation><mixed-citation xml:lang="en">Fawer M. Life cycle inventories for the production of sodium silicates / M. Fawer, M. Concannon, W. Rieber // Int. J. Life Cycle Assess. – 1999. – № 4(4). – Р. 207-212. https://doi.org/10.1007/BF02979498.</mixed-citation></citation-alternatives></ref><ref id="cit58"><label>58</label><citation-alternatives><mixed-citation xml:lang="ru">Effect of sodium hydroxide concentration on fresh properties and compressive strength of selfcompacting geopolymer concrete / F.A. Memon et al // J. Eng. Sci. Technol. – 2013. – № 8(1). – Р. 44-56.</mixed-citation><mixed-citation xml:lang="en">Effect of sodium hydroxide concentration on fresh properties and compressive strength of selfcompacting geopolymer concrete / F.A. Memon et al // J. Eng. Sci. Technol. – 2013. – № 8(1). – Р. 44-56.</mixed-citation></citation-alternatives></ref><ref id="cit59"><label>59</label><citation-alternatives><mixed-citation xml:lang="ru">Influence of Alkaline Activator Properties on Corrosion Mechanisms and Durability of Steel Reinforcement in Geopolymer Binders / М. Chira et al // Coatings. – 2025. – № 15. – Р. 734. https://doi.org/10.3390/coatings15060734.</mixed-citation><mixed-citation xml:lang="en">Influence of Alkaline Activator Properties on Corrosion Mechanisms and Durability of Steel Reinforcement in Geopolymer Binders / М. Chira et al // Coatings. – 2025. – № 15. – Р. 734. https://doi.org/10.3390/coatings15060734.</mixed-citation></citation-alternatives></ref><ref id="cit60"><label>60</label><citation-alternatives><mixed-citation xml:lang="ru">Pacheco-Torgal F. Alkali-activated binders: A review / F. Pacheco-Torgal, J. Castro-Gomes, S. Jalali // Part 2. About materials and binders manufacture. Constr. Build. Mater. – 2008. – № 22. – Р.1315-1322.</mixed-citation><mixed-citation xml:lang="en">Pacheco-Torgal F. Alkali-activated binders: A review / F. Pacheco-Torgal, J. Castro-Gomes, S. Jalali // Part 2. About materials and binders manufacture. Constr. Build. Mater. – 2008. – № 22. – Р.1315-1322.</mixed-citation></citation-alternatives></ref><ref id="cit61"><label>61</label><citation-alternatives><mixed-citation xml:lang="ru">Effect of Sodium Silicate to Sodium Hydroxide Ratios on Strength and Microstructure of Fly Ash Geopolymer Binder / M.S. Morsy et al // J. Sci. Eng. – 2014. – № 39. – Р. 4333-4339.</mixed-citation><mixed-citation xml:lang="en">Effect of Sodium Silicate to Sodium Hydroxide Ratios on Strength and Microstructure of Fly Ash Geopolymer Binder / M.S. Morsy et al // J. Sci. Eng. – 2014. – № 39. – Р. 4333-4339.</mixed-citation></citation-alternatives></ref><ref id="cit62"><label>62</label><citation-alternatives><mixed-citation xml:lang="ru">Effect of Sodium Silicate and Sodium Hydroxide Ratioson Compressive Strength of Ceramic Brick and Metakaolin Waste-Based Geopolymer Binder / М. Statkauskas et al // Materials. – 2025. – № 18. – Р. 4947. https://doi.org/10.3390/ma18214947.</mixed-citation><mixed-citation xml:lang="en">Effect of Sodium Silicate and Sodium Hydroxide Ratioson Compressive Strength of Ceramic Brick and Metakaolin Waste-Based Geopolymer Binder / М. Statkauskas et al // Materials. – 2025. – № 18. – Р. 4947. https://doi.org/10.3390/ma18214947.</mixed-citation></citation-alternatives></ref><ref id="cit63"><label>63</label><citation-alternatives><mixed-citation xml:lang="ru">Anburuvel A. The role of activators in geopolymer-based stabilization for road construction: a state-of-the-art review / A. Anburuvel // Multiscale and Multidiscip. Model. Exp. and Des. – 2023. – № 6. – Р. 41-59. https://doi.org/10.1007/s41939-022-00139-4.</mixed-citation><mixed-citation xml:lang="en">Anburuvel A. The role of activators in geopolymer-based stabilization for road construction: a state-of-the-art review / A. Anburuvel // Multiscale and Multidiscip. Model. Exp. and Des. – 2023. – № 6. – Р. 41-59. https://doi.org/10.1007/s41939-022-00139-4.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
