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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">kaz44</journal-id><journal-title-group><journal-title xml:lang="ru">Вестник Университета Шакарима. Серия технические науки</journal-title><trans-title-group xml:lang="en"><trans-title>Bulletin of Shakarim University. Technical Sciences</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2788-7995</issn><issn pub-type="epub">3006-0524</issn><publisher><publisher-name>«Шәкәрім университеті» КеАҚ</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.53360/2788-7995-2025-2(18)-57</article-id><article-id custom-type="elpub" pub-id-type="custom">kaz44-1654</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ХИМИЧЕСКАЯ ТЕХНОЛОГИЯ (ОРИГИНАЛЬНАЯ СТАТЬЯ)</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CHEMICAL TECHNOLOGY (ORIGINAL ARTICLE)</subject></subj-group></article-categories><title-group><article-title>ФИЗИЧЕСКАЯ И ХИМИЧЕСКАЯ МОДИФИКАЦИЯ ПРИРОДНОГО МИНЕРАЛА МЕСТОРОЖДЕНИЯ ЧАНКАНАЙ</article-title><trans-title-group xml:lang="en"><trans-title>PHYSICAL AND CHEMICAL MODIFICATION OF NATURAL MINERAL OF CHANKANAY DEPOSIT</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0009-0001-5325-7673</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Оразымбетова</surname><given-names>А. О.</given-names></name><name name-style="western" xml:lang="en"><surname>Orazymbetova</surname><given-names>A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Альмира Омаркызы Оразымбетова – PhD докторант кафедры «Технология неорганических инефтехимических производств»,</p><p>160012, Республика Казахстан г.Шымкент, пр.Тауке хана, 5</p></bio><bio xml:lang="en"><p>Almira Orazymbetova – PhD doctoral student of the chair «Technology of inorganic and petrochemicalindustries»,</p><p>160012, Shymkent, Republic of Kazakhstan, Tauke Khan Avenue, 5</p></bio><email xlink:type="simple">almira.oao1976@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-7913-7453</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Сагитова</surname><given-names>Г. Ф.</given-names></name><name name-style="western" xml:lang="en"><surname>Sagitova</surname><given-names>G.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Гузалия Фаритовна Сагитова – кандидат технических наук, профессор кафедры «Технологиянеорганических и нефтехимических производств»,</p><p>160012, Республика Казахстан г.Шымкент, пр.Тауке хана, 5</p></bio><bio xml:lang="en"><p>Guzaliya Sagitova – Candidate of technical sciences, Professor of the chair «Technology of inorganicand petrochemical industries»,</p><p>160012, Shymkent, Republic of Kazakhstan, Tauke Khan Avenue, 5</p></bio><email xlink:type="simple">guzalita.f1978@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-5393-8201</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Сидиков</surname><given-names>А. С.</given-names></name><name name-style="western" xml:lang="en"><surname>Sidikov</surname><given-names>A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Абдужалол Сидикович Сидиков – доктор химических наук, профессор кафедры «Общая химия,химия нефти и газа»,</p><p>Республика Узбекистан, г.Ташкент, ул. Дурмон йули, 34</p></bio><bio xml:lang="en"><p>Abdujalol Sidikov – Doctor of Chemical Sciences, Professor, of the Department «General Chemistry,Chemistry of Oil and Gas»,</p><p>Republic of Uzbekistan, Tashkent, Sapak Datka st., 2</p></bio><email xlink:type="simple">sidikov_a@mail.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-8697-9309</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Сакибаева</surname><given-names>С. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Sakibayeva</surname><given-names>S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Сауле Абдразаковна Сакибаева – кандидат технических наук, профессор кафедры«Технология неорганических и нефтехимических производств»,</p><p>160012, Республика Казахстан г.Шымкент, пр.Тауке хана, 5</p></bio><bio xml:lang="en"><p>Saule Sakibayeva – Candidate of technical sciences, Professor of the chair «Technology of inorganicand petrochemical industries»,</p><p>160012, Shymkent, Republic of Kazakhstan, Tauke Khan Avenue, 5</p></bio><email xlink:type="simple">saule.sakibayeva@bk.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-9658-5001</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Суйгенбаева</surname><given-names>А. Ж.</given-names></name><name name-style="western" xml:lang="en"><surname>Suigenbaуeva</surname><given-names>A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Алия Жолдасбековна Суйгенбаева – кандидат технических наук, доцент кафедры «Химия ифармацевтическая инженерия», </p><p>160012, Республика Казахстан г.Шымкент, пр.Тауке хана, 5</p></bio><bio xml:lang="en"><p>Aliya Suigenbaуeva – Candidate of Technical Sciences, Associate Professor, Department of Chemistry andPharmaceutical Engineering, </p><p>160012, Shymkent, Republic of Kazakhstan, Tauke Khan Avenue, 5</p></bio><email xlink:type="simple">syaljo@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru">Южно-Казахстанский университет им. М.Ауэзова<country>Казахстан</country></aff><aff xml:lang="en">M. Auezov South Kazakhstan University<country>Kazakhstan</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru">Филиал Российского государственного университета нефти и газа имени И.М. Губкина<country>Узбекистан</country></aff><aff xml:lang="en">Branch of the Russian State University of Oil and Gas named after I.M. Gubkin<country>Uzbekistan</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2025</year></pub-date><pub-date pub-type="epub"><day>08</day><month>07</month><year>2025</year></pub-date><volume>0</volume><issue>2(18)</issue><fpage>459</fpage><lpage>469</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Оразымбетова А.О., Сагитова Г.Ф., Сидиков А.С., Сакибаева С.А., Суйгенбаева А.Ж., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Оразымбетова А.О., Сагитова Г.Ф., Сидиков А.С., Сакибаева С.А., Суйгенбаева А.Ж.</copyright-holder><copyright-holder xml:lang="en">Orazymbetova A., Sagitova G., Sidikov A., Sakibayeva S., Suigenbaуeva A.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://tech.vestnik.shakarim.kz/jour/article/view/1654">https://tech.vestnik.shakarim.kz/jour/article/view/1654</self-uri><abstract><p>Разработка отечественных промоторов адгезии резин на основе минерального сырья является актуальной задачей. Образование связи с высокой и стабильной прочностью в системе эластомер-металл всегда остается в центре внимания при создании новых рецептур и новых ингредиентов. Введение солей никеля в резиновую смесь существенно повышает стабильность прочности связи в системе резина – металлокорд при действии влаги, повышенной температуры и хлористого натрия, так как в их присутствии задерживается образование слабых граничных слоев ZnO/Zn(OH)2. Интерес к цеолитам в качестве наполнителей и промоторов адгезии вызван их способностью, не только удешевлять, но и придавать качественно новые полезные свойства материалам и изделиям, возможностью задавать или корректировать эти свойства. Корректировать свойства любого минерального сырья можно модификацией. Термическая и химическая обработка цеолитов растворами кислот, щелочей и солей позволяет модифицировать цеолиты и целенаправленно изменять их свойства применительно к решению той или иной задачи. В данной работе проведена физическая и химическая модификация цеолита Чанканайского месторождения. Исследованы катионообменные свойства природного цеолита Чанканай. Ионный обмен исходного катиона кальция проводили на катионит никеля. Результат экспериментальных и физико-химических методов анализа подтверждает проникновение иона никеля на поверхность цеолита, имеющего микротвердую структуру. Было установлено, что значения степени обмена катиона Ca, содержащегося в исходном цеолите, на катионы Ni незначительна.</p></abstract><trans-abstract xml:lang="en"><p>The development of domestic rubber adhesion promoters based on mineral raw materials is a pressing task. The formation of a bond with high and stable strength in the elastomer-metal system always remains the focus of attention when creating new formulations and new ingredients. The introduction of nickel salts into the rubber mixture significantly increases the stability of the bond strength in the rubber-metal cord system under the influence of moisture, elevated temperature and sodium chloride, since in their presence the formation of weak boundary layers of ZnO/Zn(OH)2 is delayed.</p><p>Interest in zeolites as fillers and adhesion promoters is caused by their ability not only to reduce costs, but also to impart qualitatively new useful properties to materials and products, and the ability to set or adjust these properties. The properties of any mineral raw material can be adjusted through modification. Thermal and chemical treatment of zeolites with solutions of acids, alkalis and salts allows modifying zeolites and purposefully changing their properties in relation to solving a particular problem. In this work, physical and chemical modification of zeolite from the Chankanai deposit was carried out. The cation exchange properties of natural zeolite Chankanai were studied. The ion exchange of the initial calcium cation was carried out with nickel cationite. The results of experimental and physicochemical analysis methods confirm the penetration of nickel ions onto the surface of the zeolite, which has a microhard structure. It was found that the degree of exchange of the Ca cation contained in the initial zeolite for Ni cations is insignificant.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>цеолит</kwd><kwd>модификация</kwd><kwd>ионнообмен</kwd><kwd>каркас</kwd><kwd>пористый</kwd><kwd>резина</kwd><kwd>промоторов  адгезии</kwd><kwd>никель</kwd></kwd-group><kwd-group xml:lang="en"><kwd>zeolite</kwd><kwd>modification</kwd><kwd>ion exchange</kwd><kwd>framework</kwd><kwd>porous</kwd><kwd>rubber</kwd><kwd>adhesion promoters</kwd><kwd>nickel</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Шанқанай кен орнындағы цеолиттердің физика-химиялық қасиеттерін зерттеу / А.О. Оразымбетова и др. // ҚР ҰҒА Хабарлары. Химия және технология сериясы. – 2024. – Т. 2, № 459. – Б. 138-150. https://doi.org/10.32014/2024.2518-1491.228.</mixed-citation><mixed-citation xml:lang="en">Myrzalieva S.K., Pratama G.N.I.P., Khamidulla A.G. Wastewater treatment using natural zeolite materials // Complex Use of Mineral Resources. – 2021. – №2 (317). – P. 64-68.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Влияние термической обработки на сорбционные характеристики цеолита применяемого в процессе очистки воды / М.А. Сейтжанова и др. // Горение и плазмохимия. – 2023. – № 21. – С. 173-179. https://doi.org/10.18321/cpc21(3)173-179.</mixed-citation><mixed-citation xml:lang="en">Sanchez-Hernandez R., Padilla I., Lopez-Andres S., Lopez-Delgado A.  Al-Waste-Based Zeolite Adsorbent Used for the Removal of Ammonium from Aqueous Solutions // International Journal of Chemical Engineering. – 2018. – Article ID 1256197 – P. 1-11.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Myrzalieva S.K. Wastewater treatment using natural zeolite materials / S.K. Myrzalieva, G.N.I.P. Pratama, A.G. Khamidulla // Complex Use of Mineral Resources. – 2021. – № 2(317). – P. 64-68.</mixed-citation><mixed-citation xml:lang="en">Bare S.R., Knop-Gericke A., Teschner D., Havacker M., Blume R., Rocha T., Schlogl R., Chan A.S.Y., Blackwell N., Charochak M.E., Ter Veen R., Brongersma H.H. Surface analysis of zeolites: an XPS, variable kinetic energy XPS, and low energy ion scattering study // Surf. Sci. – 2016. – Vol. 648. – P. 376-382.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Al-Waste-Based Zeolite Adsorbent Used for the Removal of Ammonium from Aqueous Solutions / R. Sanchez-Hernandez et al // International Journal of Chemical Engineering. – 2018. – P. 1-11.</mixed-citation><mixed-citation xml:lang="en">Mumpton F.A. La rocamagica: uses of natural zeolites in agriculture and industry // Proc. Natl. Acad. Sci. U.S.A. – 1999. – №96 (7). – P.3463- 3470.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Туребекова Г.З. Цеолит в резиновой промышленности / Г.З. Туребекова, Н.О. Джакипбекова, С.А. Сакибаева // ЮКГУ им. М. Ауэзова, г Шымкент. http://www.dpzzz.com/en/publications/10.html.</mixed-citation><mixed-citation xml:lang="en">Li M., Zhu X., Zhu F., Ren G., Cao G., Song L. Application of modified zeolite for ammonium removal from drinking water // Desalination. – 2011. – V. 271 (1-3). – P. 29-300.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Шанқанай цеолитінің сорбциялық қасиеттеріне модификаторлар табиғатының әсері / Р.Ә. Қайыңбаева және т.б. // Қазақстанның химиялық журналы. – 2021. – Т.3, № 75. – Б. 36-46. https://doi.org/10.51580/2021-1/2710-1185.37.</mixed-citation><mixed-citation xml:lang="en">Davila-Jimenez M.M., Elizalde-Gonzalez M.P., Mattusch J., Morgenstern P., Perez-Cruz M.A., Reyes-Ortega Y., Wennrich R., Yee-Madeira H. In situ and ex situ study of the enhanced modifi cation with iro of clinoptilolite-rich zeolitic tuff for arsenic sorption from aqueous solutions. //J.Colloid.Interf.Sci. – 2008. – №322. – P. 527- 536.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Surface analysis of zeolites: an XPS, variable kinetic energy XPS, and low energy ion scattering study / S.R. Bare et al // Surf. Sci. – 2016. – Vol. 648. – P. 376-382.</mixed-citation><mixed-citation xml:lang="en">Kuldeyev E.I., Orynbekov Ye.S., Mansurov Z.A., Nurlybayev R.E., Zhumadilova Zh.O., Murzagulova  A.A. Applicability of Zeolite from the Daubabinsk and Chankanai Deposits as a Sorbent for Natural Waters // Water. – 2023. – №15(12). – P. 2231</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Мамедова Г.А. Ионообменные свойства природного цеолита морденита / Г.А. Мамедова // Тонкие химические технологии. – 2016. – Т.11, № 1. https://doi.org/10.32362/2410-6593-201611-1-29-33.</mixed-citation><mixed-citation xml:lang="en">Vladimer Tsitsishvili, Marinela Panayotova, Nato Mirdzveli, Nagima Dzhakipbekova, Vladko Panayotov, Nanuli Dolaberidze, Manana Nijaradze. Acid Resistance and Ion-Exchange Capacity of Natural Mixtures of Heulandite and Chabazite. Minerals, 2023, 13, 364. https://doi.org/10.3390/min13030364</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Mumpton F.A. La rocamagica: uses of natural zeolites in agriculture and industry / F.A. Mumpton // Proc. Natl. Acad. Sci. U.S.A. – 1999. – № 96(7). – P.3463- 3470.</mixed-citation><mixed-citation xml:lang="en">Tsitsishvili Vladimer, Dolaberidze Nanuli, Mirdzveli Nato, Nijaradze Manana, Dzhakipbekova Nagima, Harutyunyan Lusine, Amiridze Zurab , Khutsishvili Bela.  Acid treatment of Georgian, Kazakhstani and Armenian natural heulandite-clinoptilolites II. Adsorption and porous structure. (Scientific Collection «InterConf+», 31(147): with the Proceedings of the 6th International Scientific and Practical Conference «International Scientific Discussion: Problems, Tasks and Prospects» (March 19-20, 2023; Brighton, United Kingdom), InterConf, 2023, 147, 483-502, DOI 10.51582/interconf.19-20.03.2023.052</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Li M. Application of modified zeolite for ammonium removal from drinking water / Li M. et al // Desalination. – 2011. – V. 271 (1-3). – P. 29-300.</mixed-citation><mixed-citation xml:lang="en">ISTC Project No. #GE-2506. Project title  Scientific substantiation of the possibility of creating new bactericidal zeolite filter materials for purification-decontamination of water from various sources. Quarterly Technical Report. - Quarter # 3 - 2023.- p.9</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">In situ and ex situ study of the enhanced modifi cation with iro of clinoptilolite-rich zeolitic tuff for arsenic sorption from aqueous solutions / M.M. Davila-Jimenez et al // J.Colloid.Interf.Sci. – 2008. – № 322. – P. 527-536.</mixed-citation><mixed-citation xml:lang="en">In situ and ex situ study of the enhanced modifi cation with iro of clinoptilolite-rich zeolitic tuff for arsenic sorption from aqueous solutions / M.M. Davila-Jimenez et al // J.Colloid.Interf.Sci. – 2008. – № 322. – P. 527-536.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Applicability of Zeolite from the Daubabinsk and Chankanai Deposits as a Sorbent for Natural Waters / E.I. Kuldeyev et al // Water. – 2023. – № 15(12). – P. 2231.</mixed-citation><mixed-citation xml:lang="en">Applicability of Zeolite from the Daubabinsk and Chankanai Deposits as a Sorbent for Natural Waters / E.I. Kuldeyev et al // Water. – 2023. – № 15(12). – P. 2231.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Acid Resistance and Ion-Exchange Capacity of Natural Mixtures of Heulandite and Chabazite / V. Tsitsishvili et al // Minerals. – 2023. – № 13. – Р. 364. https://doi.org/10.3390/min13030364.</mixed-citation><mixed-citation xml:lang="en">Acid Resistance and Ion-Exchange Capacity of Natural Mixtures of Heulandite and Chabazite / V. Tsitsishvili et al // Minerals. – 2023. – № 13. – Р. 364. https://doi.org/10.3390/min13030364.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Acid treatment of Georgian, Kazakhstani and Armenian natural heulandite-clinoptilolites II / V. Tsitsishvili // Adsorption and porous structure. (Scientific Collection «InterConf+», 31(147): with the Proceedings of the 6th International Scientific and Practical Conference «International Scientific Discussion: Problems, Tasks and Prospects» (March 19-20, 2023; Brighton, United Kingdom), InterConf. – 2023. – № 147. – Р. 483-502. https://doi.org/10.51582/interconf.19-20.03.2023.052.</mixed-citation><mixed-citation xml:lang="en">Acid treatment of Georgian, Kazakhstani and Armenian natural heulandite-clinoptilolites II / V. Tsitsishvili // Adsorption and porous structure. (Scientific Collection «InterConf+», 31(147): with the Proceedings of the 6th International Scientific and Practical Conference «International Scientific Discussion: Problems, Tasks and Prospects» (March 19-20, 2023; Brighton, United Kingdom), InterConf. – 2023. – № 147. – Р. 483-502. https://doi.org/10.51582/interconf.19-20.03.2023.052.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Губайдуллина А.М., Корнилов А.В., Николаев К.Г. Исследование термического поведения модифицированной цеолитсодержащей кремнистой породы методами ТГ и ДТА / Губайдуллина А.М., Корнилов А.В., Николаев К.Г. // Химические науки, https://cyberleninka.ru/article/n/issledovanie-termicheskogo-povedeniya-modifitsirovannoytseolitsoderzhaschey-kremnistoy-porody-metodami-tg-i-dta.</mixed-citation><mixed-citation xml:lang="en">Губайдуллина А.М., Корнилов А.В., Николаев К.Г. Исследование термического поведения модифицированной цеолитсодержащей кремнистой породы методами ТГ и ДТА / Губайдуллина А.М., Корнилов А.В., Николаев К.Г. // Химические науки, https://cyberleninka.ru/article/n/issledovanie-termicheskogo-povedeniya-modifitsirovannoytseolitsoderzhaschey-kremnistoy-porody-metodami-tg-i-dta.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Характеристика грузинских, казахских и армянских природных геуландит-клиноптилолитов / В. Цицишвили и др. // Bull. Georgian Natl. Acad. Sci. – 2022. – № 16(4). – P.115-122.</mixed-citation><mixed-citation xml:lang="en">Характеристика грузинских, казахских и армянских природных геуландит-клиноптилолитов / В. Цицишвили и др. // Bull. Georgian Natl. Acad. Sci. – 2022. – № 16(4). – P.115-122.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Дампилова Б.В. ИК-спектроскопическое исследование природных цеолитов и их лантансодержащих форм / Б.В.Дампилова, Э.Л. Зонхоева // Сорбционные и хроматографические процессы. – 2019. – Т.19 (1). – С. 52-58. https://doi.org/10.17308/sorpchrom.2019.19/648.</mixed-citation><mixed-citation xml:lang="en">Дампилова Б.В. ИК-спектроскопическое исследование природных цеолитов и их лантансодержащих форм / Б.В.Дампилова, Э.Л. Зонхоева // Сорбционные и хроматографические процессы. – 2019. – Т.19 (1). – С. 52-58. https://doi.org/10.17308/sorpchrom.2019.19/648.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">ISTC Project No. #GE-2506. Project title Scientific substantiation of the possibility of creating new bactericidal zeolite filter materials for purification-decontamination of water from various sources. Quarterly Technical Report. – Quarter. – 2023. – № 3. – Р. 9.</mixed-citation><mixed-citation xml:lang="en">ISTC Project No. #GE-2506. Project title Scientific substantiation of the possibility of creating new bactericidal zeolite filter materials for purification-decontamination of water from various sources. Quarterly Technical Report. – Quarter. – 2023. – № 3. – Р. 9.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Павлов С.С. Исследование цеолитов, модифицированных наночастицами Ni, методом ИКспектроскопии / С.С. Павлов, Е.С. Астапова. – 2010. – № 49. https://vestnik.amursu.ru/archive/2010/49/issledovanie-tseolitov-modifitsirovannyh-nanochastitsami-ni-metodom-ikspektroskopii/.</mixed-citation><mixed-citation xml:lang="en">Павлов С.С. Исследование цеолитов, модифицированных наночастицами Ni, методом ИКспектроскопии / С.С. Павлов, Е.С. Астапова. – 2010. – № 49. https://vestnik.amursu.ru/archive/2010/49/issledovanie-tseolitov-modifitsirovannyh-nanochastitsami-ni-metodom-ikspektroskopii/.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Цинцкаладзе Г.П. ИК-спектры и каталитические свойства природных и синтетических высококремнеземных цеолитов: дис. канд. хим. наук: 02.00.04 / Цинцкаладзе Георгий Петрович. – Тбилиси, 1984. – 205 с.</mixed-citation><mixed-citation xml:lang="en">Цинцкаладзе Г.П. ИК-спектры и каталитические свойства природных и синтетических высококремнеземных цеолитов: дис. канд. хим. наук: 02.00.04 / Цинцкаладзе Георгий Петрович. – Тбилиси, 1984. – 205 с.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
