<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">kaz44</journal-id><journal-title-group><journal-title xml:lang="ru">Вестник Университета Шакарима. Серия технические науки</journal-title><trans-title-group xml:lang="en"><trans-title>Bulletin of Shakarim University. Technical Sciences</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2788-7995</issn><issn pub-type="epub">3006-0524</issn><publisher><publisher-name>«Шәкәрім университеті» КеАҚ</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.53360/2788-7995-2024-4(16)42</article-id><article-id custom-type="elpub" pub-id-type="custom">kaz44-1285</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ХИМИЧЕСКАЯ ТЕХНОЛОГИЯ (ОРИГИНАЛЬНАЯ СТАТЬЯ)</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CHEMICAL TECHNOLOGY (ORIGINAL ARTICLE)</subject></subj-group></article-categories><title-group><article-title>ИССЛЕДОВАНИЕ ВЛИЯНИЯ ФУНКЦИОНАЛИЗАЦИИ НАНО НАПОЛНИТЕЛЕЙ НА СВОЙСТВА ЭПОКСИДНЫХ КОМПОЗИТОВ</article-title><trans-title-group xml:lang="en"><trans-title>STUDY OF THE INFLUENCE OF THE FUNCTIONALIZATION OF NANO FILLERS ON THE PROPERTIES OF EPOXY COMPOSITES</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-9236-5909</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Тастанова</surname><given-names>Л. К.</given-names></name><name name-style="western" xml:lang="en"><surname>Tastanova</surname><given-names>L. K.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Лаззат Кнашевна Тастанова – кандидат химических наук, профессор кафедры нефтегазовое дело </p><p>030000, Республика Казахстан, г. Актобе, улица Молдагулова, 34 </p></bio><bio xml:lang="en"><p>Lazzat Knashevna Tastanova – candidate of chemical sciences, professor of the oil and gas department</p><p>030000, Republic of Kazakhstan, Aktobe, Moldagulova street, 34 </p></bio><email xlink:type="simple">lyazzatt@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-7038-4631</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Бекешев</surname><given-names>А. З.</given-names></name><name name-style="western" xml:lang="en"><surname>Bekeshev</surname><given-names>A. Z.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Амирбек Зарлыкович Бекешев – кандидат физико-математических наук, доцент кафедры физики </p><p> 030000, Республика Казахстан, г. Актобе, улица Молдагулова, 34 </p></bio><bio xml:lang="en"><p>Amirbek Zarlykovich Bekeshev – Candidate of Physical and Mathematical Sciences, Associate Professor of the Department of Physics </p><p>030000, Republic of Kazakhstan, Aktobe, Moldagulova street, 34 </p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-2828-9988</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Мостовой</surname><given-names>А. С.</given-names></name><name name-style="western" xml:lang="en"><surname>Mostovoy</surname><given-names>A. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Антон Станиславович Мостовой – кандидат технических наук, заведующий кафедрой естественных и математических наук, магистр наук, заведующий  лабораторией «Современные методы исследования функциональных материалов и систем»</p><p> 410054, Россия, г. Саратов, улица Политехническая, 77 </p></bio><bio xml:lang="en"><p>Anton Stanislavovich Mostovoy – candidate of technical sciences, head of the department of natural and mathematical sciences, master of science, head of the laboratory «Modern methods of research of functional materials and systems»</p><p> 410054, Russia, Saratov, Politekhnicheskaya Street, 77 </p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-6198-3018</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Орынбасар</surname><given-names>Р. О.</given-names></name><name name-style="western" xml:lang="en"><surname>Orynbasar</surname><given-names>R. O.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Райгуль Орынбасаровна Орынбасар – кандидат химических наук, доцент кафедры Нефтегазовое дело </p><p>030000, Республика Казахстан, г. Актобе, улица Молдагулова, 34 </p></bio><bio xml:lang="en"><p>Raigul Orynbassarovna Orynbassar – Candidate of Chemical Sciences, Associate Professor of the Oil and Gas Department </p><p> 030000, Republic of Kazakhstan, Aktobe, Moldagulova street, 34 </p></bio><email xlink:type="simple">raihan_06_79@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru">Актюбинский региональный университет имени К. Жубанова<country>Казахстан</country></aff><aff xml:lang="en">Aktobe Regional University named after K. Zhubanov<country>Kazakhstan</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru">Саратовский государственный технический университет имени Ю. Гагарина<country>Россия</country></aff><aff xml:lang="en">Saratov State Technical University named after Y. Gagarin<country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2024</year></pub-date><pub-date pub-type="epub"><day>27</day><month>12</month><year>2024</year></pub-date><volume>1</volume><issue>4(16)</issue><fpage>326</fpage><lpage>339</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Тастанова Л.К., Бекешев А.З., Мостовой А.С., Орынбасар Р.О., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Тастанова Л.К., Бекешев А.З., Мостовой А.С., Орынбасар Р.О.</copyright-holder><copyright-holder xml:lang="en">Tastanova L.K., Bekeshev A.Z., Mostovoy A.S., Orynbasar R.O.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://tech.vestnik.shakarim.kz/jour/article/view/1285">https://tech.vestnik.shakarim.kz/jour/article/view/1285</self-uri><abstract><p>Целью исследования является изучение влияния нанонаполнителей (наноалмазы и нитрид алюминия) и их функционализации аминоуксусной кислотой на структуру и физико-химические свойства полимерных композитов на основе эпоксидной смолы. В ходе исследования определены оптимальные концентрации аминоуксусной кислоты и, необходимые для обеспечения равномерного распределения частиц наноалмазов (НА) – 5% и нитрида алюминия (AlN) – 7,5% в полимерной матрице. Установлено, что указанные концентрации функционализирующего агента приводят к значительному повышению механических свойств композитов: в результате введения функционализированных нанонаполнителей отмечено повышение прочности на изгиб, модуля упругости, прочности на растяжение, ударопрочности и термостойкости эпоксидных композитов. Максимальное увеличение свойств составило от 6 до 50%. Наивысшие механические и термические характеристики были достигнуты при введении в композиты 0,1 масс.ч. НА и 0,05 масс.ч. AlN, это привело к увеличению термостойкости от 100-110°C до 132-168°C. Как нетронутые, так и функционализированные наночастицы приводят к повышению огнестойкости композитов, снижая потери массы и увеличивая кислородный индекс. Полученные нанокомпозитные материалы обладают исключительными механическими, термическими и пожаробезопасными свойствами, что позволяет рекомендовать их для применения в отраслях, где прочность и огнестойкость имеют решающее значение.</p></abstract><trans-abstract xml:lang="en"><p>The purpose of the study is to study the influence of nanofiller (aluminum nitride and nanoalmases) on the structure and physical and chemical properties of epoxy polymer composites and surface functionality of these nanoparticles with amino acetic acid. In the course of the study, the optimal concentrations of 5% and 7.5% of the amino acetic acid required to ensure uniform distribution of nanoalmases (NA) and aluminum nitride (AlN) particles in the polymer matrix. It was found that the listed concentrations of the functionalizing agent lead to a significant increase in the mechanical properties of composites: as a result of the introduction of functionalized nanofillers with nano-fillers, an increase in bending strength, modulus of elasticity, tensile strength, impact resistance and heat resistance of epoxy composites was observed. The maximum increase was 6-50%. 0.1 drunk. HA and 0.05 drunk.H. With the introduction of AlN, the greatest mechanical and thermal characteristics were achieved, that is, this led to an increase in heat resistance from 100-110°C to 132-168°C. Pure and functional nanoparticles have also increased fire resistance by reducing mass loss and increasing the oxygen index. In general, these nanocomposite materials have exceptional mechanical, thermal and refractory properties, which is very important for modern applications with stable strength and fire resistance.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>композит</kwd><kwd>эпоксидный олигомер</kwd><kwd>функционализация</kwd><kwd>нанонаполнитель</kwd><kwd>аминоуксусная кислота</kwd><kwd>модификация</kwd></kwd-group><kwd-group xml:lang="en"><kwd>Composite</kwd><kwd>epoxy oligomer</kwd><kwd>functionalization</kwd><kwd>nanofiller</kwd><kwd>amino acetic acid</kwd><kwd>modification</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Necar M. Mechanical and Moisture Barrier Properties of Epoxy–Nanoclay and Hybrid Epoxy–Nanoclay Glass Fibre Composites: A Review / M. Necar, A. Farhan, M.S. Mian // Polymers. – 2022. – № 14. – Р. 1620.</mixed-citation><mixed-citation xml:lang="en">References</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Review article: Polymer-matrix nanocomposites, processing, manufacturing and application: An overview / F. Hussain et al // Journal of Composite Materials. – 2006. – № 40(17). – P. 1511-1575.</mixed-citation><mixed-citation xml:lang="en">Muhammad G., Hussain M.A., Anwar F., Ashraf M. and Gilani A.H. Alhagi: a plant genus rich in bioactives for pharmaceuticals // Phytotherapy research. - 2015. - V.29. No.1. -1-13 p.     https://doi.org/10.1002/ptr.5222 (in English).</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Mihajlin YU.A. Konstrukcionnye polimernye kompozicionnye materialy / YU.A. Mihajlin. – 2-e izd. – SPb.: Nauchnye osnovy i tekhnologii. – 2010. – 822 s.</mixed-citation><mixed-citation xml:lang="en">Rakhimov K.D., Burasheva G.Sh., Ustenova G.O. Pharmacological and chemical-pharmaceutical study of herbal remedies from Alhagi kirgisorum Schrenk. - Almaty, 2018, - 394 p. http://e-kitap.kz/book/4866 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Kislova YU. Rossijskij rynok epoksidnyh smol / YU. Kislova // Kompozitnyj mir. – 2009. – № 12. – С. 20-21.</mixed-citation><mixed-citation xml:lang="en">Kukhtenko H., Bevz N., Hudz N., Datkhayev U. and Kukhtenko O. Alhagi kirghisorum schrenk: technological aspects of its thick extract for the pharmaceutical application // Agrobiodivers Improv Nutr Health Life Qual, 6, - 2022(1), - 75-84 p. https://doi.org/10.15414/ainhlq.2022.0009 (in English).</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Kadykova YU.A. Razrabotka bazal'tonapolnennyh epoksidnyh kompozitov s povyshennym kompleksom svojstv / YU.A. Kadykova // Dizajn. Materialy. Tekhnologiya. – 2012. – № 5(25). – C. 124-128.</mixed-citation><mixed-citation xml:lang="en">Zhakipbekov K., Posylkina O., Zhumabayev N., Datkhayev U., Zhumabayev N., Almurzaeva A., Mukanova A. Analysis of the current state of the pharmaceutical market of the republic of Kazakhstan // ScienceRise: Pharmaceutical Science. - 2023. - V.42. No.2. - 57 p. https://doi.org/10.15587/2519-4852.2023.267787 (in English).</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Advances and Future Outlook in Epoxy / J.S. George et al // Graphene Composites for Anticorrosive Applications. Prog. Org. Coat. – 2022. – № 162. – Р. 106571.</mixed-citation><mixed-citation xml:lang="en">Alchera F., Ginepro M., Giacalone G. Microwave-assisted extraction of polyphenols from blackcurrant by-products and possible uses of the extracts in active packaging // Foods. - 2022, V.11. No.18. - 2727 p. https://doi.org/10.3390/foods11182727 (in English).</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Wear of Epoxy Composites with Sludge Filler by Means of Cutting Tool Grinding under a ShockAbrasive Impact / A.M. Mikhalchenkov et al // J. Mach. Manuf. Reliab. – 2022. – № 51. – Р. 126-131.</mixed-citation><mixed-citation xml:lang="en">Tomasi I.T., Santos S.C., Boaventura R.A., Botelho C.M. Optimization of microwave-assisted extraction of phenolic compounds from chestnut processing waste using response surface methodology // Journal of Cleaner Production. - 2023, - V.395. - 136452 p. https://doi.org/10.1016/j.jclepro.2023.136452 (in English).</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Xiang Q. Applications of Epoxy Materials in Pavement Engineering / Q. Xiang, F. Xiao // Constr. Build. Mater. – 2020. – № 235. – Р. 117529.</mixed-citation><mixed-citation xml:lang="en">Razola-Díaz M.D., Verardo V, Guerra-Hernández EJ, García-Villanova Ruiz B, Gómez-Caravaca AM. Response Surface Methodology for the Optimization of Flavan-3-ols Extraction from Avocado By-Products via Sonotrode Ultrasound-Assisted Extraction // Antioxidants. - 2023. - V.12. No.7. - 1409 p. https://doi.org/10.1016/j.ultsonch.2021.105773 (in English).</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">A Review on the Self-Healing Ability of Epoxy Polymers / F. Zhang et al // J. Appl. Polym. Sci. – 2021. – № 138. – Р. 50260.</mixed-citation><mixed-citation xml:lang="en">Mansour H.M., Zeitoun A.A., Abd-Rabou H.S., El Enshasy H. A., Dailin D.J., Zeitoun M.A., &amp; El-Sohaimy. S.A. Antioxidant and anti-diabetic properties of olive (Olea europaea) leaf extracts: In vitro and in vivo evaluation // Antioxidants. - 2023. - V.12. No.6. - 1275 p. https://doi.org/10.3390/antiox12061275 (in English).</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Mikhal’chenkov A.M. Influence of the Concentration and Particle Size of the Filler in Epoxy – Gravel Composite on the Resistance to Contact Deformation When Introducing a Solid Sphere / A.M. Mikhal’chenkov, S.A. Fes’kov, I.V. Kozarez // Russ. Eng. Res. – 2023. – № 43. – Р. 972-975.</mixed-citation><mixed-citation xml:lang="en">Kalpoutzakis E., Chatzimitakos T., Athanasiadis V., Mitakou S., Aligiannis N., Bozinou E., Gortzi O., Skaltsounis L.A. and Lalas S.I. Determination of the total phenolics content and antioxidant activity of extracts from parts of plants from the Greek Island of Crete // Plants. - 2023. - V.12. No. 5.  - 1092 p. https://doi.org/10.3390/plants12051092 (in English).</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Malekshahinezhad K. Amine-Functionalized TiO2 Nanoparticles Covalently Loaded into Epoxy Networks via Thermal and Microwave Curing Processes / K. Malekshahinezhad, A. Ahmadikhaneghah, H. Behniafar // Macromol. Res. – 2020. – № 28. – Р. 567-572.</mixed-citation><mixed-citation xml:lang="en">Şahin B., Cakır C., Sıcak Y. and Öztürk M., Chemical composition and biological activities of essential oils and extract of Eucalyptus citriodora Hook // International Journal of Secondary Metabolite. - 2024. - V.11. No.2. - 394-407 p. https://doi.org/10.21448/ijsm.1384581 (in English).</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Mozaffarinasab H. Surface Modification of Carbon Nanotubes by a Bifunctional Amine Silane; Effects on Physical / Mechanical / Thermal Properties of Epoxy Nanocomposite / H. Mozaffarinasab, M. Jamshidi // Prog. Org. Coat. – 2023. – № 179. – Р. 107521.</mixed-citation><mixed-citation xml:lang="en">Mozaffarinasab H. Surface Modification of Carbon Nanotubes by a Bifunctional Amine Silane; Effects on Physical / Mechanical / Thermal Properties of Epoxy Nanocomposite / H. Mozaffarinasab, M. Jamshidi // Prog. Org. Coat. – 2023. – № 179. – Р. 107521.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Enhancement of Thermo-Mechanical Stability for Nanocomposites Containing Plasma Treated Carbon Nanotubes with an Experimental Study and Molecular Dynamics Simulations / Н. Jung et al // J. Sci. Rep. – 2020. – № 10. – Р. 405.</mixed-citation><mixed-citation xml:lang="en">Enhancement of Thermo-Mechanical Stability for Nanocomposites Containing Plasma Treated Carbon Nanotubes with an Experimental Study and Molecular Dynamics Simulations / Н. Jung et al // J. Sci. Rep. – 2020. – № 10. – Р. 405.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Engineering the Interfacial Adhesion in Basalt / M.C. Seghini et al // Epoxy Composites by Plasma Polymerization. Compos. Part A Appl. Sci. Manuf. – 2019. – № 122. – Р. 67-76.</mixed-citation><mixed-citation xml:lang="en">Engineering the Interfacial Adhesion in Basalt / M.C. Seghini et al // Epoxy Composites by Plasma Polymerization. Compos. Part A Appl. Sci. Manuf. – 2019. – № 122. – Р. 67-76.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">A Review on Microwave Irradiation to the Properties of Geopolymers: Mechanisms and Challenges / Y. Sun et al // Constr. Build. Mater. – 2021. – № 294. – Р. 123491.</mixed-citation><mixed-citation xml:lang="en">A Review on Microwave Irradiation to the Properties of Geopolymers: Mechanisms and Challenges / Y. Sun et al // Constr. Build. Mater. – 2021. – № 294. – Р. 123491.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Effect of Microwave Irradiation at Different Stages of Manufacturing Unsaturated Polyester Nanocomposite / А. Shcherbakov et al // Polymers. – 2022. – № 14. – Р. 4594.</mixed-citation><mixed-citation xml:lang="en">Effect of Microwave Irradiation at Different Stages of Manufacturing Unsaturated Polyester Nanocomposite / А. Shcherbakov et al // Polymers. – 2022. – № 14. – Р. 4594.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Domingues D. The Use of an Electric Field in the Preparation of Glass Fibre/ D. Domingues, E. Logakis, A.A. Skordos // Epoxy Composites Containing Carbon Nanotubes. Carbon. – 2012. – № 50. – Р. 2493-2503.</mixed-citation><mixed-citation xml:lang="en">Domingues D. The Use of an Electric Field in the Preparation of Glass Fibre/ D. Domingues, E. Logakis, A.A. Skordos // Epoxy Composites Containing Carbon Nanotubes. Carbon. – 2012. – № 50. – Р. 2493-2503.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Tests of Physicochemical and Mechanical Strength Properties of Polymer Composites on an Epoxy Resin Matrix / Е. Miekos et al // Modified by a Constant Magnetic Field. Materials. – 2022. – № 15. – Р. 6730.</mixed-citation><mixed-citation xml:lang="en">Tests of Physicochemical and Mechanical Strength Properties of Polymer Composites on an Epoxy Resin Matrix / Е. Miekos et al // Modified by a Constant Magnetic Field. Materials. – 2022. – № 15. – Р. 6730.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Hetemi D. Surface Functionalisation of Polymers / D. Hetemi, J. Pinson // Chem. Soc. Rev. – 2017. – № 46. – Р. 5701-5713.</mixed-citation><mixed-citation xml:lang="en">Hetemi D. Surface Functionalisation of Polymers / D. Hetemi, J. Pinson // Chem. Soc. Rev. – 2017. – № 46. – Р. 5701-5713.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Reinforcement of Epoxy Resin by Additives of Amine-Functionalized Graphene Nanosheets / T.Y. Yung et al // Coatings. – 2021. – № 11. – Р. 35.</mixed-citation><mixed-citation xml:lang="en">Reinforcement of Epoxy Resin by Additives of Amine-Functionalized Graphene Nanosheets / T.Y. Yung et al // Coatings. – 2021. – № 11. – Р. 35.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Study on the Mechanical and Toughness Behavior of Epoxy Nano-Composites with ZeroDimensional and Two-Dimensional Nano-Fillers / X. Li et al // Polymers. – 2022. – № 14. – Р. 3618.</mixed-citation><mixed-citation xml:lang="en">Study on the Mechanical and Toughness Behavior of Epoxy Nano-Composites with ZeroDimensional and Two-Dimensional Nano-Fillers / X. Li et al // Polymers. – 2022. – № 14. – Р. 3618.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Highly Thermally Conductive Epoxy Composites with AlN/BN Hybrid Filler as Underfill Encapsulation Material for Electronic Packaging / W.A. Lee Sanchez et al // Polymers. – 2022. – № 14. – Р. 2950.</mixed-citation><mixed-citation xml:lang="en">Highly Thermally Conductive Epoxy Composites with AlN/BN Hybrid Filler as Underfill Encapsulation Material for Electronic Packaging / W.A. Lee Sanchez et al // Polymers. – 2022. – № 14. – Р. 2950.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Schrand A.M. Nanodiamond Particles: Properties and Perspectives for Bioapplications / A.M. Schrand, S.A.C. Hens, O.A. Shenderova // Crit. Rev. Solid State Mater. Sci. – 2009. – № 34. – Р. 18-74.</mixed-citation><mixed-citation xml:lang="en">Schrand A.M. Nanodiamond Particles: Properties and Perspectives for Bioapplications / A.M. Schrand, S.A.C. Hens, O.A. Shenderova // Crit. Rev. Solid State Mater. Sci. – 2009. – № 34. – Р. 18-74.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Mechanical Properties of Epoxy Composites with High Contents of Nanodiamond / I. Neitzel et al // Compos. Sci. Technol. – 2011. – № 71. – Р. 710-716.</mixed-citation><mixed-citation xml:lang="en">Mechanical Properties of Epoxy Composites with High Contents of Nanodiamond / I. Neitzel et al // Compos. Sci. Technol. – 2011. – № 71. – Р. 710-716.</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Kim S.-H. Amine-Terminated Chain-Grafted Nanodiamond/ S.-H. Kim, K.Y. Rhee, S.-J. Park // Epoxy Nanocomposites as Interfacial Materials: Thermal Conductivity and Fracture Resistance. Compos. Part B Eng. – 2020. – № 192. – Р. 107983.</mixed-citation><mixed-citation xml:lang="en">Kim S.-H. Amine-Terminated Chain-Grafted Nanodiamond/ S.-H. Kim, K.Y. Rhee, S.-J. Park // Epoxy Nanocomposites as Interfacial Materials: Thermal Conductivity and Fracture Resistance. Compos. Part B Eng. – 2020. – № 192. – Р. 107983.</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Surface Functionalization and Structure Characterizations of Nanodiamond and Its Epoxy Based Nanocomposites / Y.A. Haleem et al // Compos. Part B Eng. – 2015. – № 78. – Р. 480-487.</mixed-citation><mixed-citation xml:lang="en">Surface Functionalization and Structure Characterizations of Nanodiamond and Its Epoxy Based Nanocomposites / Y.A. Haleem et al // Compos. Part B Eng. – 2015. – № 78. – Р. 480-487.</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Coordinating Mechanical Performance and Fire Safety of Epoxy Resin via Functionalized Nanodiamond / Q. Wang et al // Diam. Relat. Mater. – 2020. – № 108. – Р. 107964.</mixed-citation><mixed-citation xml:lang="en">Coordinating Mechanical Performance and Fire Safety of Epoxy Resin via Functionalized Nanodiamond / Q. Wang et al // Diam. Relat. Mater. – 2020. – № 108. – Р. 107964.</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Effect of Phosphorus and Chlorine Containing Plasticizers on the Physicochemical and Mechanical Properties of Epoxy Composites / A. Bekeshev et al // J. Compos. Sci. – 2023. – № 7. – Р. 178.</mixed-citation><mixed-citation xml:lang="en">Effect of Phosphorus and Chlorine Containing Plasticizers on the Physicochemical and Mechanical Properties of Epoxy Composites / A. Bekeshev et al // J. Compos. Sci. – 2023. – № 7. – Р. 178.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
